The mechanical properties of polymer encapsulating materials change considerably when packages are exposed to elevated temperatures for longer times.Here we report a systematic study on the change in viscoelastic properties of a commercial molding compound which is stored at 175℃ for periods of time ranging up to 4 weeks. It is shown that instead of the expected degradation, the modulus and the glass transition temperature increased and that these effects are accompanied with a relatively large amount of shrinkage. All effects can be interpreted in terms of the formation of an oxidized layer where extra crosslinking occurred.
IntroductionMolding compounds are highly filled epoxy resins which are used to encapsulate electronic devices such that the device is protected against mechanical, environmental and chemical attacks. However, during and after the molding process shrinkage of the molding compound results in residual stresses and warpage which negatively affects product life and reliability. In order to be able to predict and minimize these stresses a reliable model of the material properties of these molding compounds is indispensable. A complicating factor is that the properties of molding compounds are not constant. The material is viscoelastic, meaning that the modulus changes with time and temperature. Furthermore, the viscoelastic behavior changes considerably during cure and more slowly during storage afterwards (physical aging). In the past much effort was done to characterize the change in mechanical properties of these materials during as well as directly after the molding process [1]. After implementing these detailed material models in finite element software it was shown for example that warpage of molded packages could be accurately predicted [2].Nowadays electronic packages are also used in automotive applications where they are mounted close to the engine. In these applications repeated exposure to temperatures of 200℃ or more frequently occurs and the question arises whether the molding compound material remains stable under these conditions or not. It was expected that after prolonged exposure to high temperatures the polymer chains would break down [3], resulting in a lower glass transition temperature and a lower modulus. However, in literature also studies which show an increase in the glass transition temperature can be found [4]. Preliminary experiments showed that this was also happening to our molding compound. Apart from ref. [4], surprisingly little studies can be found which report this increase in glass transition temperature and accompanied other changes in mechanical properties after prolonged exposure to high temperatures.