Effect of Pyrolysis Carbon Black from Waste Tire on the Mechanical Properties of SSBR/BR Blend

Abstract

Pyrolysis carbon black (PCB) is a main product during the pyrolysis of waste tires. Using PCB to partially replace carbon black has drawn great attention. Herein, PCB is used to replace commercial carbon black N234 in a solution‐polymerized styrene‐butadiene rubber (SSBR)/butadiene rubber (BR)/silica compound used for tire treads. The influence of liquid polyisoprene (LIR) on the SSBR/BR/silica compound is studied. The scorch time of the compound is prolonged and the curing rate increases when N234 is partially replaced by PCB, and the processing performance of the compound is improved after the addition of LIR. As N234 is partially replaced by PCB, the addition of LIR can increase the tensile strength and elongation at break of SSBR/BR/silica vulcanizates, and improve their ageing resistance. When 50% N234 is replaced by PCB in the presence of LIR, the rolling resistance and wet grip of SSBR/BR/silica vulcanizate are improved, while the abrasion resistance slightly decreased. In the presence of liquid polyisoprene, PCB can be successfully used to partially replace common carbon black in tire rubber compounds without compromising properties.

Effect of TESPT on viscoelastic and mechanical properties with the morphology of SSBR/BR hybrid nanocomposites

“…3 To balance these contradictory viscous and elastic properties, different blends of synthetic and natural rubbers are used on the tire tread formulations; so a difficult problem for researchers around the world is to develop an ideal compound that balances the properties of the magic triangle. 4 In this regard, green tires have been developed and these tires, in addition to having low rolling resistance had a suitable wet grip. The optimum formulation is a compound made of silica as the main filler and an SSBR copolymer with high vinyl content as the main rubber and silane coupling agents.…”