2006
DOI: 10.1111/j.1478-4408.2006.00020.x
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Effect of sulphonation level upon the fixation and build up properties of reactive dyes

Abstract: A number of closely related dyes, each possessing a single β‐sulphatoethyl sulphonyl reactive group and a variable number of sulphonate residues, were prepared and their dyeing behaviour evaluated. As the level of sulphonation of the dyes increased, both fixation efficiency and build up on cotton were reduced. These observations were attributed to increased electrostatic repulsion, between dye and fibre, as the anionicity, or level of sulphonation, of the dyes was increased. In support of this, the build up of… Show more

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Cited by 4 publications
(4 citation statements)
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“…It is also clear that the increment of K / S values was slower when dye concentration was over 55 g/L. As more Blue 222 molecules were fixed on the fibers, there were less available sites for further reactions, leading to a slow increasing trend of K / S values at higher dye concentration [3]. Compared with untreated cotton fabrics, the K / S values and dye fixation rates of dyed cationic fabrics were enhanced by 39.4% and 14.3% at the maximum values, respectively.…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…It is also clear that the increment of K / S values was slower when dye concentration was over 55 g/L. As more Blue 222 molecules were fixed on the fibers, there were less available sites for further reactions, leading to a slow increasing trend of K / S values at higher dye concentration [3]. Compared with untreated cotton fabrics, the K / S values and dye fixation rates of dyed cationic fabrics were enhanced by 39.4% and 14.3% at the maximum values, respectively.…”
Section: Resultsmentioning
confidence: 99%
“…Cotton is one of the most widely used natural polymer fibers in textiles and is usually dyed with reactive dyes [1,2]. For reactive dyeing of cotton, electrostatic interaction between the dye and the fiber mainly determine the final color performance [3]. Large quantities of inorganic salts (NaCl or Na 2 SO 4 ) need to be added into dye bath to enhance the utilization of reactive dyes [4].…”
Section: Introductionmentioning
confidence: 99%
“…Also the IR spectra of all dyes revealed absorption bands of OH group at 3420-3444 cm -1 . 1 HNMR spectra of dyes 3 and 5 revealed the appearance of two triplets at 3.57-3.63 ppm and 3.94-4.00 ppm due to methylene proton of the sulphatoethylsulphone group.…”
Section: Characterization Of the Ureido Reactive Dyes 1-5mentioning
confidence: 99%
“…The IR Spectra were recorded on a Nexus 670 Fourier Transform-infrared (FTIR) spectrophotometer (KBr discs). 1…”
Section: Measurements and Analysismentioning
confidence: 99%