Volumetric liquid side mass transfer, bubble size distribution, and bubble shape was measured in a vertically oriented semi-batch gas-liquid Taylor-Couette vortex reactor with an aspect ratio of Γ=h/(r o -r i )=40 and radius ratio of η=r i /r o =0.75. Azimuthal Reynolds number, Axial Reynolds number and Capillary number were varied between 0 to 3.8×10 4 , 7 to 99, and 6.1×10 -6 to 76.0×10 -6 , respectively. Power-law correlations based on these data were presented for dimensionless Sauter mean diameter and Sherwood number in terms of the dimensionless parameters. Presence of ethanol as surfactant in the liquid was shown to inhibit bubble coalescence, which in addition to lowering interfacial surface tension causes a generally smaller bubble size at higher concentrations of surfactant. It was also shown that the mass transfer coefficient generally increases with higher concentrations of surfactant. Both the bubble diameter and mass transfer are influenced more at lower concentrations of surfactant, and the introduction of higher amount of ethanol causes a decrease in both parameters.
Keywords
Gas-liquid mass transfer, Surfactant, Sherwood number, Taylor-Couette vortex bioreactor. The addition of surfactant decreases bubble size Nomenclature Roman a Specific gas-liquid interfacial surface area [m 2 /m 3 ] C Concentration [mg/L] d Bubble diameter [mm] D Diffusion coefficient [m 2 /s] E Ellipticity of spheroid g Gravitational acceleration [m/s 2 ] h Axial distance from the bottom of reactor [m] k Volumetric mass transfer coefficient [m/s] l Spheroid major diameter [m] m Spheroid minor diameter [m] N Impeller (inner cylinder) rotational speed [rev/s] Q Volumetric flow rate [L/min] r i Outer radius of the inner cylinder [m] r o Inner radius of the outer cylinder [m] u Superficial velocity [m/s] Greek Γ Reactor aspect ratio (Γ=h/(r o -r i )) ε G Gas holdup η Reactor radius ratio (η=r i /r o ) ω Rotational speed of the inner cylinder [rad/s]