Heat transfer in shell and tube heat exchangers is in general described in terms of the relationships of Nuselt, Prandtl, and Reynold dimensionless numbers. One of the parameters of heat exchanger performance is convective heat transfer coefficient (h), and mathematical model can predict it. This study aimed to find out the relationship of the parameters that affected the performance of vertical tubular baffle internal reboiler during ethanol distillation. The mathematical model was developed by a dimensional analysis with the π-Buckingham method. Several influencing parameters during the distillation process were identified to develop a mathematical model. The study was carried out on the distillation process of low-concentration ethanol, i.e., 10%, 20%, 30% using internal reboilers with different tube sizes, i.e., diameters of 1.27 cm, 2.54 cm, 3.81 cm and height of 4 cm, 6 cm, 8 cm, to obtain the value of h observation. Based on the results of the study, a heat transfer model was obtained, i.e., 𝑵𝒖 = 𝟏𝟒𝟓𝟐. 𝟐𝟗 𝑹𝒆 𝟎.𝟑𝟓𝟕 ( 𝑫 𝑳