“…The biocarbon prepared using such biomass resources offers (i) relatively low internal resistance, (ii) superior electrical conductivity, (iii) outstanding cyclic stability, (iv) admirable chemical stability, and (v) excellent reaction kinetics. − Numerous synthesis techniques, i.e., hydrothermal technique, chemical bath deposition (CBD), electrodeposition, successive ionic layer adsorption and reaction (SILAR), and spray pyrolysis, were reported to prepare various biocarbon nanostructures in the form of a film/powder. Among them, spraying a direct solution over a hot substrate for obtaining a film-type electrode is a cost-effective, safe, and uncomplicated synthesis technique to operate, by which the structure, phase, and morphology can be easily controlled by regulating various parameters such as, spray rate, operating temperature, flow rate, deposition time, etc. , …”