Toward establishing the full design aspects of chitosan
as a packaging
material or as cling wraps, the chemical characteristics, thermal
stability, optical transparency, Young’s modulus, elongation
at fracture, and burst strength of pure and glycerol-added 100 μm-thick-chitosan
films were investigated. Films of chitosan and films with 10%, 20%,
and 30% w/w glycerol as the plasticizer were prepared per standard
protocols. Electron microscopic analysis revealed that all films are
homogeneous. The addition of glycerol did not alter the crystallinity,
lowered the glass transition by ∼7 °C, decreased the thermal
stability, decreased the roughness by 50%, and increased the optical
transparency by 5%. It was found that the incorporation of glycerol
decreased the Young’s modulus by two orders, increased the
plastic strain at least by four times, and decreased the burst strength
by at least two times. The results from this systematic analysis,
including comparisons with existing packaging materials, provide a
holistic picture for tailoring the properties of chitosan-based packaging
materials for modified atmosphere packaging (MAP) toward sustainable
development.