The oxidative stability of Tengjiao (Zanthoxylum schinifolium) Oil with added single or compound antioxidants were studied by Schaal-oven test according to the peroxide value (PV) and acid value (AV) .The results indicate that, TBHQ be used as the single antioxidant, the optimum amount was 0.015%, the affection more than 0.015% was not obvious. TBHQ be used as the compound antioxidant, the minimum amount of significant antioxidant activity was 0.01%, and the best amount was 0.015% TBHQ + 0.005% AP, which was better than 0.015% and 0.02% TBHQ.