The growth of TiN films by plasma-enhanced atomic layer deposition is investigated using tetrakis-(dimethylamino) titanium and NH 3 . In particular, the influence of the NH 3 plasma pulse time on the deposited film is discussed in detail. It is found that the film resistivity decreases monotonically to 4.6 × 10 −4 Ω • cm by increasing the NH 3 plasma pulse time to 25 s, then shows an increase. The former trend is ascribed to some competitive reactions dominated by N radicals and residual O 2 , i.e., more N radicals originating from longer NH 3 plasma pulses produce more Ti-N bonds and restrain the formation of Ti-O and Ti-C bonds in the deposited film. The latter trend is attributed to the generation of additional Ti, N, and C active sites at the saturated bonding surface due to plasma ion bombardment; these can react with residual O 2 , producing more C-O and Ti-O bonds.Smooth, ultra-thin TiN films (<3 nm) are also successfully demonstrated.