“…The discovery of the giant MCE in Gd 5 Si 2 Ge 2 [10] prompted worldwide research to exploit first-order magneto-structural transitions (MSTs) to achieve large MCEs. As a result, a number of materials exhibiting giant magnetocaloric effects, such as those based on La-Fe-Si [11], Fe 2 P [12], MnTX (T = transition metal, X = p-block element) [13,14], MnAs [15,16], and some Heusler alloys [17], were discovered and characterized. These state-ofthe-art materials are, unfortunately, far from ideal: some contain hazardous, critical or non-earth-abundant elements, while others involve complex syntheses and processing.…”