LiFePO 4 /carbon complexes were prepared by electrospinning to improve rate performance at high C-rate and their electrochemical properties were investigated to be used as a cathode active material for lithium ion battery. The LiFePO 4 /carbon complexes were prepared by the electrospinning method. The prepared samples were characterized by SEM, EDS, XRD, TGA, electrometer, and electrochemical analysis. The LiFePO 4 /carbon complexes prepared have a continuous structure with carbon-coated LiFePO 4 and the LiFePO 4 in LiFePO 4 /carbon complex has improved thermal stability from carbon coating. The conductivity of LiFePO 4 /carbon complex heat-treated at 800°C is measured as 2.23 9 10 -2 S cm -1 , which is about 10 6 -10 7 times more than that of raw LiFePO 4 . The capacity ratio of coin cell manufactured from raw LiFePO 4 is 40%, whereas the capacity ratio of coin cell manufactured from LiFePO 4 /carbon complex heat-treated at 800°C is 61% (10 C/0.1 C). The improved rate performance of LiFePO 4 /carbon complex heat-treated at 800°C is due to the carbon coating and good electrical connection.