To improve the permeability of wood, three chemical reagents
were
used to pretreat Chinese fir, white oak, and poplar. Through a factorial
experiment with the mass change rate of the wood as the indicator,
NaOH was preliminarily selected as the pretreatment agent. Further
orthogonal experiments were conducted to explore the effects of NaOH
concentration, temperature, and treatment time on the mass change
rate, dye uptake rate, transverse dye penetration rate, and color
difference of the wood. A fuzzy, comprehensive analysis was used to
optimize the pretreatment process. The results showed that after NaOH
pretreatment, the highest mass change rates of Chinese fir, white
oak, and poplar were 11.30, 10.66, and 8.53%, respectively. Compared
with untreated wood, the dye uptake rate of three wood species increased
by 1.05, 1.43, and 1.13 times, respectively; the radial dye penetration
rate increased by 5.05, 4.14, and 3.38 times, respectively; and the
tangential dye penetration rate increased by 3.91, 3.45, and 3.84
times, respectively. These findings indicate an enhancement in permeability
for all three wood species following NaOH pretreatment. The brightness
of the three wood species decreased after NaOH pretreatment, while
the yellow and red colors increased in Chinese fir and poplar and
decreased in white oak. Scanning electron microscopy showed that pits
in the wood opened after pretreatment, while extractives decreased.
Infrared spectroscopy analysis indicated varying degrees of extraction
effects from NaOH pretreatment across the three wood species, along
with increased active hydroxyl groups within the wood structure. X-ray
diffraction analysis revealed that NaOH dissolved noncrystalline substances
in wood, leading to improved crystallinity. These experimental findings
provide essential data for future endeavors in wood pretreatment and
subsequent staining processes.