“…In addition, the content of oxygen vacancies can be roughly estimated by the relative peak intensity ratio (RIR = I lattice /I non-lattice ) of lattice oxygen to nonlattice oxygen and the peak area ratio of Fe 3þ to Fe 2þ . [18,26] That is, the lower value of RIR or the peak area ratio of Fe 3þ to Fe 2þ represents the higher concentration of oxygen vacancies. For the BFO thin films with thicknesses of 70, 110, 150, 180, and 220 nm, the RIR values are 6.66, 4.34, 3.22, 2.43, and 2.08 respectively; the peak area ratios of Fe 3þ to Fe 2þ are 3.82, 2.49, 2.3, 1.91, and 1.68 respectively.…”