Effects of pH, temperature, and ionic strength on adsorption of sodium dodecylbenzenesulfonate into Mg–Al–CO3 layered double hydroxides

Reis, Márcio José dos; Silvério, Fabiano; Tronto, Jairo; Valim, João Barros

doi:10.1016/j.jpcs.2003.09.020

Cited by 118 publications

(25 citation statements)

References 10 publications

Supporting

Mentioning

Contrasting

Unclassified

Order By: Relevance

“…It was observed an irregular shape of the LDH, with high porosity and some clustering. This morphology was similar to those obtained by Reis et al for Mg-Al-CO 3 LDH [19] . These materials will test as adsorbents of pesticides and herbicides in contaminated waters 20 .…”

Section: Resultssupporting

confidence: 91%

Synthesis of Co-Al-Cl LDH by cathodic material reprocessing from cellular phone batteries

et al. 2014

View full text Add to dashboard Cite

The aim of this paper was the recovering of the cathodic material from discarded lithium ion batteries for obtainment of the lamellar double hydroxides (LDHs) by the co-precipitation method at variable pH in HCl and H 2 O 2 1:1 (v/v) acid solution containing Co and Al (extracted from cathodic material composed of LiCoO 2 and aluminum foil). These metals were precipitated in LiOH at pH 9 or 11, or NH 4 OH at pH 9 and submitted to the hydrothermal treatment (HT) to improve the structural organization of the LDHs lamellae. After precipitation, the resulting solids were structurally characterized by XRD for phase identification and calculation of the unit cell parameter, thermally by TGA for the identification of the mass loss and morphologically by SEM. The sample obtained by precipitation with LiOH at pH 11 / hydrothermal treatment showed diffraction peaks similar to hydrotalcite, morphological and thermal characteristics similar to the pattern Co-Al-Cl LDH obtained by co-precipitation at constant pH 8. Keywords: lithium ion batteries, LiCoO 2 and aluminum foil recovering, reprocessing of cellular phone battery and lamellar double hydroxides

show abstract

Section: Resultssupporting

confidence: 91%

Synthesis of Co-Al-Cl LDH by cathodic material reprocessing from cellular phone batteries

et al. 2014

View full text Add to dashboard Cite

show abstract

“…Changes in the signal intensity-to-basis width ratios of the (003) reflections could be interpreted as an indicator for OM sorption to the entrance of the interlayer space of the minerals. The attenuation of the reflections can be also explained by OM diminishing the reflection intensity, as observed by Hussein et al (2001) and dos Reis et al (2004).…”

Section: Alteration Of the Adsorbentmentioning

confidence: 67%

“…Layered double hydroxides are known for their unique anion exchange properties (e.g., Newman and Jones, 1998) which allows for various organic or inorganic anions to be present in the interlayer space. Recently, the sorption of organic compounds such as anionic organic toxicants (Ulibarri et al, 1995), pesticides (Celis et al, 2000;Inacio et al, 2001), lignite-derived humic acids (Seida and Nakano, 2000), or surfactants (dos Reis et al, 2004) has been studied intensively. Except for some studies on sorption of OM from upland surface and peat water (Amin and Jayson, 1996;Hussein et al, 2001), information on the adsorption of natural OM to hydrotalcite is scarce and non-detailed.…”

Section: Introductionmentioning

confidence: 99%

Hydrotalcite—A potentially significant sorbent of organic matter in calcareous alkaline soils

Grünewald¹,

Kaiser²,

Jahn³

2008

Geoderma

View full text Add to dashboard Cite

“…These compounds are frequently found in surface and ground waters, becoming a major environmental and human health problem. For this reason, the interest in the removal of these compounds has increased and a variety of adsorbents have been investigated including layered double hydroxides (LDHs) [2].…”

Section: Introductionmentioning

confidence: 99%

“…Their structure consists of positively charged metal hydroxides with interlayer anions and water, with their chemical composition represented by * [5]. Based on the anionic exchange capacity and intercalation aptitudes, the LDHs are typically used as adsorbents in environmental pollution management, such as the removal of dye [6,7], chlorophenols [8,9], oxyanions [10,11], CO oxidation [12,13], sorption of metal cations [14] and surfactants [15][16][17][18][19][20].…”

Section: Introductionmentioning

confidence: 99%

Synthesis and physicochemical characterization of ZnMgNiAl-CO3-layered double hydroxide and evaluation of its sodium dodecylbenzenesulfonate removal efficiency

Tiar

Boutahala

Benhouria

et al. 2016

Desalination and Water Treatment

View full text Add to dashboard Cite

In this study, the adsorption of anionic surfactant by uncalcined ZnMgNiAl-CO 3 was examined using sodium dodecylbenzenesulfonate (SDBS) as a model compound in an aqueous solution. The synthesized adsorbent (ZnMgNiAl-CO 3 ) was characterized by FTIR, X-ray diffraction, and BET. The capacity of ZnMgNiAl-CO 3 to adsorb surfactant was evaluated at different contact times, pH values, mass effect, and initial surfactant concentrations. According to the obtained results, the adsorption processes could be described by a pseudosecond-order kinetic model. The adsorption isotherm was well fitted by the Sips model. Maximum adsorption capacity for SDBS on ZnMgNiAl-CO 3 was found to be 191.7 mg/g which was in accordance with the experimental value. Thermodynamic parameters were estimated as well, and their values indicated that the adsorption process was spontaneous and endothermic. The values of ΔH˚and ΔS˚of the adsorption process were 7.9 and 0.102 kJ/mol, respectively. The low value of ΔH˚(<40 kJ/mol) indicated that adsorption process occurs mainly through a physical means.

show abstract

Effects of pH, temperature, and ionic strength on adsorption of sodium dodecylbenzenesulfonate into Mg–Al–CO3 layered double hydroxides

Cited by 118 publications

References 10 publications

Synthesis of Co-Al-Cl LDH by cathodic material reprocessing from cellular phone batteries

Synthesis of Co-Al-Cl LDH by cathodic material reprocessing from cellular phone batteries

Hydrotalcite—A potentially significant sorbent of organic matter in calcareous alkaline soils

Synthesis and physicochemical characterization of ZnMgNiAl-CO3-layered double hydroxide and evaluation of its sodium dodecylbenzenesulfonate removal efficiency

Contact Info

Product

Resources

About