To improve inkjet printing performance,
surface single encapsulation
of nano-TiO2 particles has widely been reported. However,
surface single encapsulation has a limited effect on improving the
inkjet printing performance of nano-TiO2 particles. In
this study, SiO2 nanoparticle-decorated TiO2 (SiO2/TiO2) nanocomposites modified with silane
coupling agents were obtained by a two-step method to improve the
inkjet printing performance. The effects of different Na2SiO3 concentrations on the morphology, particle size,
and opacity performance of SiO2/TiO2 nanocomposites
were studied. The results showed that when the molar ratio of Na2SiO3 to TiO2 was 0.06:1, SiO2/TiO2 nanocomposites showed the best dispersibility and
the best opacity performance. Then, the effect of different silane
coupling agents on the properties of curing films was investigated.
The results showed that the properties (opacity performance, tensile
properties, thermal stability, and color fastness) of the KH570-SiO2/TiO2 nanocomposite curing film were greatly improved.
The characteristic peaks in the Fourier transform infrared (FTIR)
and X-ray photoelectron spectroscopy (XPS) confirmed that SiO2 nanoparticles were anchored at the nano-TiO2 particle
surface via Si–O–Ti bonds, and silane coupling agents
were successfully grafted onto the SiO2/TiO2 nanocomposite surface via Si–O–Si/Si–O–Ti
bonds. In addition, it was verified that the double bonds of KH570-SiO2/TiO2 nanocomposites participated in the photopolymerization
of oligomers/monomers by FTIR.