In this paper, a thorough investigation
of cadmium sulfide nanoparticle
characteristics has been studied as a result of the wide attention
and enormous application in a solar cell. Perovskite-sensitized solar
cells (PSSCs) are a favorably effectual and sanitary hybrid, organic–inorganic
solar cell device. The simple way uses synthesized cost-effective
CdS quantum dots (QDs) via the sol–gel approach and also investigates
their structural, electronic, and vibrational properties of CdS nanoparticles
with the density functional theory method in B3LYP. Moreover, we use
high-resolution transmission electron microscopy (HRTEM) techniques
to confirm our calculations and acquire good agreement to the structural
analysis of CdS QD formation. The maximum grain diameter is obtained
from a HRTEM image, at ∼4 nm. The particle size analyzer that
obtained ∼4 nm of CdS QD nanoparticles was determine via a
dynamic light scattering study. The results demonstrated that the
fabricated CdS QD-based dye-sensitized solar cell and PSSC represented
a maximum power conversion efficiency (η) of 0.5 and 1.8% at
1 sun condition. This efficiency was improved by approximately 72%,
associated with that of the reference cell.