Effects of temperature on the crystal and molecular structure of the mixed-valence linear chain bis(ethylenediamine)platinum bis(ethylenediamine)dihaloplatinum tetraperchlorate (halo = chloro, bromo)

Huckett, Sara C.; Scott, Brian L.; Love, Steven P.; Donohoe, Robert J.; Burns, Carol J.; García, Eva Vivar; Frankcom, Tracey M.; Swanson, Basil I.

doi:10.1021/ic00062a044

Cited by 41 publications

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“…1) is a very strong CDW example with an intervalence charge transfer (IVCT) band edge near 500 nm ͑ഠ2.5 eV͒. The material is a well-formed crystal with a homogeneous lattice consisting of quasi-1D chains of chloride-bridged Pt͑en͒ 2 units, with each unit having two associated ClO 4 2 counterions [11]. The CDW ground state consists of alternating nominal Pt 12 and Pt 14 sites with a corresponding distortion of the chloride ions toward the Pt 14 site.…”

mentioning

confidence: 99%

“…1. Structure of ͕͓Pt͑en͒ 2 ͔ ͓Pt͑en͒ 2 Cl 2 ͔ ͑ClO 4 ͒ 4 ͖ (en ethylenediamine; H atoms are omitted) [11]. One PtCl chain is shown on the left.…”

mentioning

confidence: 99%

“…Ground state results for less strongly nonlinear MX cases (e.g., PtBr, PtI [8,9,11]), as well as localized excited state dynamics [18] and competitions with impurity localization, will be considered in future work.…”

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confidence: 99%

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Observation of Intrinsically Localized Modes in a Discrete Low-Dimensional Material

et al. 1999

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We report the experimental observation of intrinsic dynamically localized vibrational states in crystals of the highly nonlinear halide-bridged mixed-valence transition metal complex ͕͓Pt͑en͒ 2 ͔ ͓Pt͑en͒ 2 Cl 2 ͔ ͑ClO 4 ͒ 4 ͖, where en ethylenediamine. These states are identified by the distinctive structure and strong redshifts they impose upon the overtone resonance Raman spectra. Quantitative modeling of the observed redshifts is presented based on a nonadiabatic coupled electron-lattice model that self-consistently predicts strong nonlinearity and highly localized multiquanta bound states.[S0031-9007(99)08915-2]

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confidence: 99%

“…1. Structure of ͕͓Pt͑en͒ 2 ͔ ͓Pt͑en͒ 2 Cl 2 ͔ ͑ClO 4 ͒ 4 ͖ (en ethylenediamine; H atoms are omitted) [11]. One PtCl chain is shown on the left.…”

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confidence: 99%

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Observation of Intrinsically Localized Modes in a Discrete Low-Dimensional Material

et al. 1999

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“…le). [7]). The image reveals two different rows of patterns of different heights aligned along the b-direction.…”

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confidence: 99%

Surface structure of MX-Chains studied by atomic force microscopy

Bar¹,

Scott²,

Johnson³

et al. 1995

Synthetic Metals

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“…28.61 (14) C5 ii -Pt2-S1 ii 92.44 (11) N3 i -Pt1-C3 151.39 (14) C5-Pt2-S1 ii 87.56 (11) S1 i -Pt1-C3 85.28 (10) S1-Pt2-S1 ii 180 S1-Pt1-C3 94.72 (10 Huckett et al (1993); (d) Toriumi et al (1993); (e) Endres et al (1979).…”

Section: Sup-5unclassified

A one-dimensional platinum mixed-valence complex with bridging thiocyanate S atoms: [[Pt^II(en)₂](μ-SCN)[Pt^IV(en)₂](μ-SCN)](ClO₄)₄(en is ethane-1,2-diamine)

2013

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A new one-dimensional platinum mixed-valence complex with nonhalogen bridging ligands, namely catena-poly[[[bis(ethane-1,2-diamine-κ(2)N,N')platinum(II)]-μ-thiocyanato-κ(2)S:S-[bis(ethane-1,2-diamine-κ(2)N,N')platinum(IV)]-μ-thiocyanato-κ(2)S:S] tetrakis(perchlorate)], {[Pt(2)(SCN)(2)(C(2)H(8)N(2))(4)](ClO(4))(4)}(n), has been isolated. The Pt(II) and Pt(IV) atoms are located on centres of inversion and are stacked alternately, linked by the S atoms of the thiocyanate ligands, forming an infinite one-dimensional chain. The Pt(IV)-S and Pt(II)···S distances are 2.3933 (10) and 3.4705 (10) Å, respectively, and the Pt(IV)-S···Pt(II) angle is 171.97 (4)°. The introduction of nonhalogen atoms as bridging ligands in this complex extends the chemical modifications possible for controlling the amplitude of the charge-density wave (CDW) state in one-dimensional mixed-valence complexes. The structure of a discrete Pt(IV) thiocyanate compound, bis(ethane-1,2-diamine-κ(2)N,N')bis(thiocyanato-κS)platinum(IV) bis(perchlorate) 1.5-hydrate, [Pt(SCN)(2)(C(4)H(8)N(2))(2)](ClO(4))(2)·1.5H(2)O, has monoclinic (C2) symmetry. Two S-bound thiocyanate ligands are located in trans positions, with an S-Pt-S angle of 177.56 (3)°.

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Effects of temperature on the crystal and molecular structure of the mixed-valence linear chain bis(ethylenediamine)platinum bis(ethylenediamine)dihaloplatinum tetraperchlorate (halo = chloro, bromo)

Cited by 41 publications

References 0 publications

Observation of Intrinsically Localized Modes in a Discrete Low-Dimensional Material

Observation of Intrinsically Localized Modes in a Discrete Low-Dimensional Material

Surface structure of MX-Chains studied by atomic force microscopy

A one-dimensional platinum mixed-valence complex with bridging thiocyanate S atoms: [[Pt^II(en)₂](μ-SCN)[Pt^IV(en)₂](μ-SCN)](ClO₄)₄(en is ethane-1,2-diamine)

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Effects of temperature on the crystal and molecular structure of the mixed-valence linear chain bis(ethylenediamine)platinum bis(ethylenediamine)dihaloplatinum tetraperchlorate (halo = chloro, bromo)

Cited by 41 publications

References 0 publications

Observation of Intrinsically Localized Modes in a Discrete Low-Dimensional Material

Observation of Intrinsically Localized Modes in a Discrete Low-Dimensional Material

Surface structure of MX-Chains studied by atomic force microscopy

A one-dimensional platinum mixed-valence complex with bridging thiocyanate S atoms: [[PtII(en)2](μ-SCN)[PtIV(en)2](μ-SCN)](ClO4)4(en is ethane-1,2-diamine)

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A one-dimensional platinum mixed-valence complex with bridging thiocyanate S atoms: [[Pt^II(en)₂](μ-SCN)[Pt^IV(en)₂](μ-SCN)](ClO₄)₄(en is ethane-1,2-diamine)