Here we found that viscoelastic features of molasses
facilitate
paste formation with wheat bran and rice straw powders, and a subsequent
heat treatment results in significant hardening with dehydration
and the Maillard reaction. This simple two-step process (i.e., blending
and heating) was beneficial to fabricate diverse 3-dimensional shapes.
The hardening process displayed around 3.5, 0.5, and 2.5 MPa as compressive,
tensile, and flexural strengths, respectively, when a 1:1 (v/v) ratio of molasses and the biomass
powders was used. Instrumental analyses on molasses before and after
the heat process and hardening with a model compound (i.e., gallic
acid) revealed that structural transformations of molasses based on
the Maillard reactions and concomitant coupling reactions with lignin
or polyphenolic moieties from the biomass are crucial for the phenomenon.
Practical functionalities such as antibacterial, nonbiodegradable,
and virus particle-adsorbing properties potentially attributable to
the lignin and melanoidin contents were also exhibited with the composites.