Effects of the Structure of Benzenesulfonate-Based Draw Solutes on the Forward Osmosis Process

Abstract

A series of phosphonium-based ionic liquids (ILs) based on benzenesulfonate derivatives (tetrabutylphosphonium benzenesulfonate ([TBP][BS]), tetrabutylphosphonium 4-methylbenzenesulfonate ([TBP][MBS]), tetrabutylphosphonium 2,4-dimethylbenzenesulfonate ([TBP][DMBS]), and tetrabutylphosphonium 2,4,6-trimethylbenzenesulfonate ([TBP][TMBS])) were synthesized via anion exchange with tetrabutylphosphonium bromide ([TBP][Br]). Then, we characterized the ILs and investigated their suitability as draw solutes for forward osmosis (FO), focusing on their thermoresponsive properties, conductivities, and osmotic pressures. We found that aqueous [TBP][BS] was not thermoresponsive, but 20 wt% aqueous [TBP][MBS], [TBP][DMBS], and [TBP][TMBS] had lower critical solution temperatures (LCSTs) of approximately 41, 25, and 21 °C, respectively, enabling their easy recovery using waste heat. Based on these findings, 20 wt% aqueous [TBP][DMBS] was tested for its FO performance, and the water and reverse solute fluxes were found to be approximately 9.29 LMH and 1.37 gMH, respectively, in the active layer facing the draw solution (AL-DS) mode and 4.64 LMH and 0.37 gMH, respectively, in the active layer facing the feed solution (AL-FS) mode. Thus, these tetrabutylphosphonium benzenesulfonate-based LCST-type ILs are suitable for drawing solutes for FO process.

State-of-the-Art of Polymer/Fullerene C60 Nanocomposite Membranes for Water Treatment: Conceptions, Structural Diversity and Topographies

“…Usually, membrane technologies have been claimed for having low cost, fine workability, efficiency, low energy ingesting, and scale-up viabilities [ 5 ]. Pressure-driven membranes processes have been applied in conventional membrane filtration [ 6 ]. Polymeric membranes have been identified for the high permeability, the stability, the selectivity, the salt rejection, and the low working pressure.…”