A series of phosphonium-based ionic liquids (ILs) based on benzenesulfonate derivatives (tetrabutylphosphonium benzenesulfonate ([TBP][BS]), tetrabutylphosphonium 4-methylbenzenesulfonate ([TBP][MBS]), tetrabutylphosphonium 2,4-dimethylbenzenesulfonate ([TBP][DMBS]), and tetrabutylphosphonium 2,4,6-trimethylbenzenesulfonate ([TBP][TMBS])) were synthesized via anion exchange with tetrabutylphosphonium bromide ([TBP][Br]). Then, we characterized the ILs and investigated their suitability as draw solutes for forward osmosis (FO), focusing on their thermoresponsive properties, conductivities, and osmotic pressures. We found that aqueous [TBP][BS] was not thermoresponsive, but 20 wt% aqueous [TBP][MBS], [TBP][DMBS], and [TBP][TMBS] had lower critical solution temperatures (LCSTs) of approximately 41, 25, and 21 °C, respectively, enabling their easy recovery using waste heat. Based on these findings, 20 wt% aqueous [TBP][DMBS] was tested for its FO performance, and the water and reverse solute fluxes were found to be approximately 9.29 LMH and 1.37 gMH, respectively, in the active layer facing the draw solution (AL-DS) mode and 4.64 LMH and 0.37 gMH, respectively, in the active layer facing the feed solution (AL-FS) mode. Thus, these tetrabutylphosphonium benzenesulfonate-based LCST-type ILs are suitable for drawing solutes for FO process.

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Thermo-responsive ionic compounds having lower critical solution temperature were utilized as a draw solute for eco-sustainable forward osmosis.

A series of thermo-responsive tetrabutylphosphonium 1-alkanesulfonates (abbreviated as [P 4444 ][C n S], n = 6, 8, 10, and 12), where n is the number of carbon atoms in the alkyl group on the 1-alkanesulfonate anion, were prepared by an ion-exchange reaction to investigate their potential ability toward the application of draw solutes in forward osmosis (FO). We systematically studied the recovery properties and FO performance ofThis series exhibited lower critical solution temperature (LCST) characteristics, which offer a clear advantage of being energy-efficient for recovering draw solutes; however, [P 4444 ][C 6 S] was only observed at 20 wt %. The LCSTs of the 20 wt % [P 4444 ][C 6 S], [P 4444 ][C 8 S], [P 4444 ][C 10 S], and [P 4444 ]-[C 12 S] draw solutions were approximately 83, 54, 49, and 56 °C, respectively. Moreover, when the orientation of the active layer was heading toward the draw solution (AL-DS mode), the water and reverse solute flux of [P 4444 ][C 10 S] were about 1.58 LMH and 0.81 gMH, respectively, at 20 wt % aqueous solutions. When the membrane was used in the active layer facing the feed solution (AL-FS) system, the water and reverse solute flux of [P 4444 ][C 10 S] were approximately 0.71 LMH and 0.38 gMH, respectively, at 20 wt % aqueous solutions. Thus, this study is the first to examine the structural transformations of the bulkier alkyl group on the sulfonate anion moiety and its feasibility as the new draw solute for the FO system.