Environmental monitoring of the area of influence of pollutants of sewage is inextricably linked with the state of atmospheric air parameters, which determines the final characteristics of the process. In this case, this interaction has a significant impact on the development and functioning, as well as the durability of plant components of ecosystems. Increasing the accuracy and reliability of monitoring results is due to the economic difficulties due to the high cost of equipment (detectors, communication channels, multiplexing devices, security systems, etc.). The aim of the research is to optimize the measuring monitoring network of toxic pollutants, taking into account the number and location of pollutant detectors. The simplest developed method is based on taking into account the radius of the area of reliable detection, which depends on the signal threshold of detection, which in turn depends on the background pollution and its fluctuations in the control locations, the distance from the source of the emissions, the time of exposure of the detector (or the processing time of the analysis), the level the actions of the control system (the values of pollution, the achievement of which should trigger an alarm system to exceed the maximum permissible value of pollution), flow velocity.The system approach to the analysis of heavy technogenic accidents and their ecological consequences is aimed at the coordination and integration of the use of scientific research, the holistic coverage of the phenomena of interest, the deepening of the study of the mechanism of accidents, the development of emergency processes in space and time, the impact of the impressive factors of the accident on the environment. The developed methodology for the analysis of the toxic pollutions, including waste with hexamethylenediamine, is built on a hierarchical principle, consisting of blocks of analysis of accidents, examination of the consequences of accidents, a priori and a posteriori risk assessment, as well as the adoption of managerial decisions.