A novel spoof surface plasmon polaritons (SSPP) structure is applied to the design of radio frequency (RF) power amplifiers (PAs) in this work. Both standard SSPP and the proposed SSPP structures are used as input and output matching networks of a multioctave PA design. An analysis and discussion of the electromagnetic characteristics of the proposed SSPP structures is presented. Further optimization of PA performance is achieved by utilizing the gradient algorithm of the Advanced Design System tool. According to the test results, the newly developed SSPP‐based PA achieves output power ranging from 40.5 to 42.6 dBm, while the power additional efficiency varies between 60% and 66.55%, with a total layout size of 59.8 mm × 14.6 mm in the frequency band of 0.8–3.2 GHz. In comparison with recent published work, the PA designed in this work expands the bandwidth while maintaining high output power and efficiency while being smaller in size.