The lower luminous efficiency is a critical issue for ultraviolet light-emitting diodes (UV-LEDs) owing to the poor carrier injection efficiency and high dislocation density. Here, we can improve the luminous efficiency in two avenues by adjusting the Al composition of the InGaN/AlxGa1-xN pre-well superlattice. First, due to the strain-induced piezoelectric and intrinsic spontaneous polarization, a large number of electrons gather at the InGaN/AlxGa1-xN interface, which improves the electron concentration of the pre-well superlattice and lowers the conduction band energy of the first quantum barrier layer (FQB), thus enhancing the electron injection efficiency. Second, the pre-well superlattice can act as a hole blocking layer to prevent holes from leaking into the n-type layer and confine them in the quantum well layer. As the Al composition increases, the hole blocking effect of the pre-well superlattice is strengthened. However, higher Al composition decreases the lattice quality, which makes it possible for carrier loss through defect-related non-radiative recombination. Finally, the output power of the samples with 5% Al composition in the pre-well superlattice is 5.9% and 102.5% higher than that of the samples with 3% and 7% Al composition, respectively.