Efficient covalent functionalisation of carbon nanotubes: the use of “click chemistry”

Clavé, Guillaume; Campidelli, Stéphane

doi:10.1039/c1sc00342a

Cited by 63 publications

(40 citation statements)

References 92 publications

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“…16) [303]. The emergence of new or re-actualised synthetic methods (known under the term of ''click chemistry'') has the potential to provide an elegant protocol to prepare heteroatomcontaining NCNTs, especially O-containing NCNTs [401].…”

Section: Preparation Of O-containing Ncntsmentioning

confidence: 99%

One-dimensional nitrogen-containing carbon nanostructures

Ćirić‐Marjanović

Pašti

Mentus

2015

Progress in Materials Science

115

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Section: Preparation Of O-containing Ncntsmentioning

confidence: 99%

One-dimensional nitrogen-containing carbon nanostructures

Ćirić‐Marjanović

Pašti

Mentus

2015

Progress in Materials Science

115

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“…Adronov et al polymerised styrene using ATRP and grafted this to the surface of SWCNTs using a Cu(I) catalysed azide-alkyne [3 + 2] cycloaddition (CuAAC). 31 The 'graft to' approach enables specific control of polymer architecture but limits grafting density due to sterics from chains giving a mushroom like coverage as opposed to a brush type architecture.…”

Section: Introductionmentioning

confidence: 99%

Functionalisation of MWCNTs with poly(lauryl acrylate) polymerised by Cu(0)-mediated and RAFT methods

et al. 2016

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Permanent WRAP URL:http://wrap.warwick.ac.uk/79040 Copyright and reuse:The Warwick Research Archive Portal (WRAP) makes this work of researchers of the University of Warwick available open access under the following conditions. Copyright © and all moral rights to the version of the paper presented here belong to the individual author(s) and/or other copyright owners. To the extent reasonable and practicable the material made available in WRAP has been checked for eligibility before being made available.Copies of full items can be used for personal research or study, educational, or not-for-profit purposes without prior permission or charge. Provided that the authors, title and full bibliographic details are credited, a hyperlink and/or URL is given for the original metadata page and the content is not changed in any way. Publisher statement:First published by Royal Society of Chemistry 2016 http://dx.doi.org/10.1039/C6PY00522E A note on versions:The version presented here may differ from the published version or, version of record, if you wish to cite this item you are advised to consult the publisher's version. Please see the 'permanent WRAP URL' above for details on accessing the published version and note that access may require a subscription. Poly (

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“…1,4,5 Incorporation of CNTs into polymers induces many attractive properties such as mechanical, electrical and thermal conductive properties, remotely actuated shape memory, electromagnetic interference shielding and sensing capability of the polymer matrix. [6][7][8][9][10][11][12][13][14] Chemical functionalization by covalently linking functional groups to the CNT surface will break the integral sp 2 conformation of the carbon atoms, resulting in the dramatic decrease of electrical and mechanical properties of the functionalized CNTs. [6][7][8][9][10][11][12][13][14] Chemical functionalization by covalently linking functional groups to the CNT surface will break the integral sp 2 conformation of the carbon atoms, resulting in the dramatic decrease of electrical and mechanical properties of the functionalized CNTs.…”

Section: Introductionmentioning

confidence: 99%

Block-assembling: a new strategy for fabricating conductive nanoporous materials from nanocomposites based on a melt-miscible crystalline/crystalline blend and MWCNTs

Shi

et al. 2015

J. Mater. Chem. C

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As featured in:www.rsc.org/MaterialsC Showcasing research from the group of Prof. Yongjin Li, College of Materials, Chemistry and Chemical Engineering, Hangzhou Normal University.Block-assembling: a new strategy for fabricating conductive nanoporous materials from nanocomposites based on a melt-miscible crystalline/crystalline blend and MWCNTsConductive nanoporous materials were obtained from a "block-assembling" structure in ternary nanocomposites comprised of a melt-miscible crystalline/crystalline blend and MWCNTs, by selective removal of the component with poor capability of crystallization. See Yongjin Li et al., J. Mater. Chem. C, 2015, 3, 8510. 8510 | J. Mater. Chem. C, 2015, 3, 8510--8518 This journal is In this work, we focus on exploring a new method to prepare conductive nanoporous polymeric materials, by simply incorporating multi-walled carbon nanotubes (MWCNTs) into melt-miscible poly(L-lactic acid)/ poly(oxymethylene) (PLLA/POM) blends. The POM components in the ternary nanocomposites crystallize first to form ''nano-hybrid shish-kebab (NHSK)'' structures at a high temperature in the presence of MWCNTs, with the simultaneous exclusion of poorly crystallizable PLLA chains into the intra-NHSK regimes.The subsequent PLLA crystallization in the intra-NHSK regimes is also nucleated on the surface of MWCNTs and transforms the final crystal morphology into ''ternary-hybrid shish-kebab (THSK)'' superstructures.Therefore, a ''binary-polymer-decoration'' of MWCNTs, named ''block-assembling'', is achieved. Such a novel ''block-assembling'' structure is further used to fabricate conductive nanoporous polymeric materials with a unique interposition structure of CNTs in the inner wall of the internal pores after the removal of the PLLA components in the ternary nanocomposites.

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Efficient covalent functionalisation of carbon nanotubes: the use of “click chemistry”

Cited by 63 publications

References 92 publications

One-dimensional nitrogen-containing carbon nanostructures

One-dimensional nitrogen-containing carbon nanostructures

Functionalisation of MWCNTs with poly(lauryl acrylate) polymerised by Cu(0)-mediated and RAFT methods

Block-assembling: a new strategy for fabricating conductive nanoporous materials from nanocomposites based on a melt-miscible crystalline/crystalline blend and MWCNTs

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