Efficient removal of dyes and heavy metal ions from waste water using Gum ghatti – graft – poly(4-acryloylmorpholine) hydrogel incorporated with magnetite nanoparticles

Kulal, Prajwal; Vishalakshi, B.

doi:10.1016/j.jece.2020.104207

Cited by 86 publications

(19 citation statements)

References 50 publications

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“…Therefore, removing organic dyes prior to entering the environment has gained pivotal importance for protecting public health. Several techniques such as membrane filtration, precipitation, coagulation, photocatalysis, ion exchange, chemical and microbial degradation, and the adsorption process have been exploited to prevent dyes from damaging the environment …”

Section: Introductionmentioning

confidence: 99%

Facile Synthesis of Polyaniline@UiO-66 Nanohybrids for Efficient and Rapid Adsorption of Methyl Orange from Aqueous Media

Mirzaei

Jafarpour

Shojaei

et al. 2022

Ind. Eng. Chem. Res.

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A series of UiO-66/polyaniline (UiO-66/PANI) nanohybrids with various UiO-66 to aniline weight ratios ranging from 0.01 to 0.1 was synthesized using an in situ polymerization technique. The adsorption behavior of the neat PANI nanofiber network and the synthesized nanohybrids was examined toward anionic methyl orange (MO) dye from aqueous media. It was realized that the maximum adsorption capacity of PANI (229 mg/g) increases steadily by increasing the UiO-66 content in the nanohybrid up to 7 wt % at 426 mg/g, and then, it approximately levels off at 432 mg/g for the nanohybrid sample containing 10 wt % UiO-66, that is, UP10. Based on a thorough characterization, it was shown that UiO-66 is completely encapsulated by PANI nanofibers. Further adsorption examinations on the nanohybrids exhibited that the Langmuir isotherm model and pseudo-second-order kinetics model best describe the adsorption performance of all the prepared adsorbents during the adsorption of MO. Meanwhile, thermodynamic investigations demonstrated that the adsorption of MO onto UP10 is endothermic and spontaneous, and entropy controls the adsorption process. UP10 exhibited high selectivity indices of 100, 20, and 34 for the adsorption of MO as an anionic dye over crystal violet (CV), malachite green (MG), and methylene blue (MB), respectively, as cationic dyes.

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Section: Introductionmentioning

confidence: 99%

Facile Synthesis of Polyaniline@UiO-66 Nanohybrids for Efficient and Rapid Adsorption of Methyl Orange from Aqueous Media

Mirzaei

Jafarpour

Shojaei

et al. 2022

Ind. Eng. Chem. Res.

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“…Several parallel mechanisms occur for the oxidation of Hg 0 elaborated in successive equations. Different multicomponent nanohybrids employed for adsorptional removal of HMs are summarized in Table 4 (121)(122)(123)(124)(125)(126)(127)(128)(129)(130)(131)(132)(133)(134)(135)(136)(137)(138)(139)(140).…”

Section: 𝐴𝐴𝐼𝐼𝐷𝐷𝑃𝑃𝑃𝑃 𝐷𝐷𝐷𝐷𝑃𝑃𝑃𝑃𝑝𝑝 𝑝𝑝𝑃𝑃𝑃𝑃𝑃𝑃𝑒𝑒𝑃𝑃𝑃𝑃𝐴𝐴mentioning

confidence: 99%

Photocatalytic and Adsorptional Removal of Heavy Metals from Contaminated Water using Nanohybrids

Guleria

2021

Materials Research Foundations

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Water contaminated with heavy metals is a major menace for aquatic life and human health consequently its efficient removal remains a crucial challenge for researcher. The utilization of various photocatalytic nanohybrids to synergistically photo-reduce and adsorb heavy metals is a potent strategy to combat water pollution. This book chapter give an overview of the fundamental principle of photocatalysis and various single, binary, ternary and quaternary nanohybrids employed for simultaneous photoreduction and adsorption of heavy metals with its mechanistic insight. Further, conclusion and future prospective as well as limitation of available nanohybrids were addressed. We hope that this book chapter dispenses some noticeable information to heavy metal ions removal from polluted water.

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“…5 The SI in H 2 O was calculated as 45.8% ± 2.7 higher than previously reported values for films containing Priamine 1074. 18 Since Priamine 1074 is derived from fatty acids, it provides hydrophobicity to the films in which it is present, but in this case, ACMO is water-soluble, 19,20 so the final photocurable thermosets show a water resistance balance between their hydrophobic and hydrophilic components.…”

Section: Photocurable Thermosets and Degradation Studymentioning

confidence: 99%

Bio‐based and hydrolytically degradable hydroxyurethane acrylates as photocurable thermosets

Younes

Marić

2021

J of Applied Polymer Sci

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This study focuses on the synthesis of bio-based and hydrolytically degradable photocurable thermosets made from hydroxyurethane acrylates (HUA). The hydroxyurethanes (HUs) are prepared from the reaction between ethylene carbonate and a bio-based diamine, Priamine 1074. Subsequently, the HU initiates the ring opening polymerization of ε-caprolactone (CL), resulting in telechelic groups of 5 CL units at both ends of the HU. The resulting HU-CL 5 is finally acrylated to prepare the degradable HUA (HU-CL 5 -A) with transformations confirmed following each step via proton nuclear magnetic resonance ( 1 H-NMR) and Fourier-transform infrared (FTIR) spectroscopies. HU-CL 5 -A is photocured with 4-acryloylmorpholine (ACMO) as a photosensitive reactive diluent. The photocurable thermosets exhibit slight water swelling (swelling index of 46%), as Priamine 1074 and ACMO are hydrophobic and hydrophilic, respectively, leading to the slow and partial degradation of the films in water at 85 C for 14 days. The cleavage of the CL units from the film networks is proven via 1 H-NMR and FTIR, which demonstrates the main objective of this study in synthesizing photocurable and degradable HUA resins.

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Efficient removal of dyes and heavy metal ions from waste water using Gum ghatti – graft – poly(4-acryloylmorpholine) hydrogel incorporated with magnetite nanoparticles

Cited by 86 publications

References 50 publications

Facile Synthesis of Polyaniline@UiO-66 Nanohybrids for Efficient and Rapid Adsorption of Methyl Orange from Aqueous Media

Facile Synthesis of Polyaniline@UiO-66 Nanohybrids for Efficient and Rapid Adsorption of Methyl Orange from Aqueous Media

Photocatalytic and Adsorptional Removal of Heavy Metals from Contaminated Water using Nanohybrids

Bio‐based and hydrolytically degradable hydroxyurethane acrylates as photocurable thermosets

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