Efficient synthesis for large-scale production and characterization for hydrogen storage of ligand exchanged MOF-74/174/184-M (M = Mg2+, Ni2+)

Oh, Hyunchul; Maurer, Stefan; Balderas‐Xicohténcatl, Rafael; Arnold, Lena; Magdysyuk, Oxana V.; Schütz, Gisela; Müller, Ulrich; Hirscher, Michael

doi:10.1016/j.ijhydene.2016.08.153

Cited by 56 publications

(20 citation statements)

References 34 publications

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“…By comparing the features of final products obtained using MARM and UARM methods, it seems that the Th‐MOF sample synthesized using MARM method had more distinct features, which could highly affect the adsorption applications of the samples. The BET technique revealed that the surface area equaled approximately 2240 m 2 /g for the Th‐MOF samples prepared using the MARM, a value which was not only higher than that of the previous sample, but also considerable compared to that of other MOF nanostructures synthesized by different routes such as ultrasonic, hydrothermal, microwave and slow diffusion methods …”

Section: Resultsmentioning

confidence: 99%

A novel microwave assisted reverse micelle fabrication route for Th (IV)‐MOFs as highly efficient adsorbent nanostructures with controllable structural properties to CO and CH₄ adsorption: Design, and a systematic study

Sargazi

Afzali

Mostafavi

2019

Applied Organom Chemis

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Reducing gas contaminants by affordable and effective adsorbents is a major challenge in the 21st century. In the present study, thorium metal organic framework (Th‐MOF) nanostructures are introduced as highly efficient adsorbents. These compounds were manufactured via a novel route resulting from the development of microwave assisted reverse micelle (MARM) and ultrasound assisted reverse micelle (UARM) methods. The products were characterized utilizing XRD, SEM, TGA/DSC, BET, and FT‐IR analyses. Based on the results, the samples synthesized by MARM had uniform size distribution, high thermal stability, and significant surface area. Calculations using DFT/B3LYP indicated that the compounds have a tendency to the polymeric form, which could theoretically confirm the formation of Th‐MOF. Results of analysis of variance (ANOVA) showed that synthesis parameters played a critical role in the manufacturing of products with distinctive properties. Response surface methodology (RSM) predicted the possibility of creating Th‐MOF adsorbents with the surface area of 2579 m2/g, which was a considerable value in comparison with the properties of other adsorbents. Adsorption studies showed that, in the optimum conditions, the Th‐MOF products had high adsorption capacity for CO and CH4. It is believed that the synthesis protocol developed in the present study and the systematic studies conducted on the samples which lead to products with ideal adsorption properties.

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Section: Resultsmentioning

confidence: 99%

A novel microwave assisted reverse micelle fabrication route for Th (IV)‐MOFs as highly efficient adsorbent nanostructures with controllable structural properties to CO and CH₄ adsorption: Design, and a systematic study

Sargazi

Afzali

Mostafavi

2019

Applied Organom Chemis

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“…This method has commonly been used for MOF solvent exchange (Mg-MOF-74, Mg-MOF-174, Mg-MOF-184, MIL-100, etc.) [73] , [76] on the laboratory scale, but it is expected to also be capable of processing a large amount of MOFs with an industrial extractor. Such industrial equipment has capacities from 100 to 1000 L depending on the type and size.…”

Section: Mof Mass Production Processesmentioning

confidence: 99%

Recent advances in process engineering and upcoming applications of metal–organic frameworks

Ryu

Jee

Rao

et al. 2021

Coordination Chemistry Reviews

297

138

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“…As previously mentioned, in 2000 the German chemical company BASF started to explore the commercial potential of MOFs. BASF is focused on commercializing MOF solutions [160,252] for the transportation industry [253] and is partnering with several technology, development and original equipment manufacturers to pilot the use of MOF materials for enhanced natural gas storage in vehicles in Europe, Asia and North America. Vehicles equipped with natural gas fuel systems, containing MOF materials, were introduced by BASF in 2013 [254].…”

Section: Gas Storagementioning

confidence: 99%

Metal–organic frameworks in Germany: From synthesis to function

Evans

Garai

Reinsch

et al. 2019

Coordination Chemistry Reviews

107

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Metal-organic frameworks (MOFs) are constructed from a combination of inorganic and organic units to produce materials which display high porosity, among other unique and exciting properties. MOFs have shown promise in many wide ranging applications, such as catalysis and gas separations. In this review, we highlight MOF research conducted by Germany-based research groups. Specifically, we feature approaches for the synthesis of new MOFs, high-throughput MOF production, advanced characterization methods and examples of advanced functions and properties.

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Efficient synthesis for large-scale production and characterization for hydrogen storage of ligand exchanged MOF-74/174/184-M (M = Mg2+, Ni2+)

Cited by 56 publications

References 34 publications

A novel microwave assisted reverse micelle fabrication route for Th (IV)‐MOFs as highly efficient adsorbent nanostructures with controllable structural properties to CO and CH₄ adsorption: Design, and a systematic study

A novel microwave assisted reverse micelle fabrication route for Th (IV)‐MOFs as highly efficient adsorbent nanostructures with controllable structural properties to CO and CH₄ adsorption: Design, and a systematic study

Recent advances in process engineering and upcoming applications of metal–organic frameworks

Metal–organic frameworks in Germany: From synthesis to function

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Efficient synthesis for large-scale production and characterization for hydrogen storage of ligand exchanged MOF-74/174/184-M (M = Mg2+, Ni2+)

Cited by 56 publications

References 34 publications

A novel microwave assisted reverse micelle fabrication route for Th (IV)‐MOFs as highly efficient adsorbent nanostructures with controllable structural properties to CO and CH4 adsorption: Design, and a systematic study

A novel microwave assisted reverse micelle fabrication route for Th (IV)‐MOFs as highly efficient adsorbent nanostructures with controllable structural properties to CO and CH4 adsorption: Design, and a systematic study

Recent advances in process engineering and upcoming applications of metal–organic frameworks

Metal–organic frameworks in Germany: From synthesis to function

Contact Info

Product

Resources

About

A novel microwave assisted reverse micelle fabrication route for Th (IV)‐MOFs as highly efficient adsorbent nanostructures with controllable structural properties to CO and CH₄ adsorption: Design, and a systematic study

A novel microwave assisted reverse micelle fabrication route for Th (IV)‐MOFs as highly efficient adsorbent nanostructures with controllable structural properties to CO and CH₄ adsorption: Design, and a systematic study