This article proposes a new method of identity recognition in sanitary facilities based on electrocardiography (ECG) signals. Our team previously proposed a novel approach of invisible ECG at the thighs using polymeric electrodes, leading to the creation of a proof-of-concept system integrated into a toilet seat. In this work, a biometrics pipeline was devised, which tested four different classifiers, varying the population from 2 to 17 subjects and simulating a residential environment. However, for this approach to be industrially viable, further optimization is required, particularly regarding electrode materials that are compatible with industrial processes. As such, we also explore the use of a conductive silicone material as electrodes, aiming at the industrial-scale production of a toilet seat capable of recording ECG data, without the need for body-worn devices. A desirable aspect when using such a system is matching the recorded data with the monitored user, ideally using a minimal sensor set, further reinforcing the relevance of user identification through ECG signals collected at the thighs. Our approach was evaluated against a reference device for a population of 17 healthy and pathological individuals, covering a wide age range (24–70 years). With the silicone composite, we were able to acquire signals in 100% of the sessions, with a mean heart rate deviation between a reference system and our experimental device of 2.82 ± 1.99 beats per minute (BPM). In terms of ECG waveform morphology, the best cases showed a Pearson correlation coefficient of 0.91 ± 0.06. For biometric detection, the best classifier was the Binary Convolutional Neural Network (BCNN), with an accuracy of 100% for a population of up to four individuals.