Ein makrobicyclischer Tris‐bipyridin‐Ligand sowie ein Cu‐ und ein Ag‐Komplex

Mendoza, Javier de; Mesa, Esther; Rodríguez‐Ubis, Juan Carlos; Vázquez, Purificación; Vögtle, Fritz; Windscheif, Paul-Michael; Rissanen, Kari; Lehn, Jean‐Maríe; Lilienbaum, Daniel; Ziessel, Raymond

doi:10.1002/ange.19911031025

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2023

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Cited by 25 publications

(2 citation statements)

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“…They typically formed cascade complexes, wherein the anion is entrapped in between two metal centers located at the poles of the cryptand [18,19] . Reports on iminocryptates incorporating more than two metal cations are very scarce [20,21] …”

Section: Introductionmentioning

confidence: 99%

Plenates: Anion‐Dependent Self‐Assembly of the Pyrrole Cage Encapsulating Silver(I) Clusters

Sarwa

Białońska

Garbicz

et al. 2023

Chemistry A European J

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The self-assembly of 2,5-diformylpyrrole, tris(2aminoethyl)amine, and silver(I) yielded, depending on the size and basicity of the anion, new cascade complexes or plenates, that is, cryptates incorporating Ag n n + clusters. The nature of the product was counterion-dependent, and its formation was either driven by cascade anion binding or by argentophilic interactions stabilizing the cluster within the cavity. The reaction of plenates with tetrabutylammonium halides resulted in the protonation-coupled replacement of the Ag 3 3 + with anion(s), yielding cascade cryptates.

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Section: Introductionmentioning

confidence: 99%