Einige Valene von benzanellierten fünfgliedrigen Heteroarenen – Synthesen und NMR‐Spektren

The easily available vinyl sulfone 3 showed great potential for new applications in several fields such as organic synthesis and bioconjugate formation. This was demonstrated by performing a systematic assessment of its reactivity in Michael, radical, and cycloaddition reactions. Heteroaryl vinyl sulfone 3 presented excellent output in terms of reactivity and selectivity, proving superior to phenyl vinyl sulfone 1 and with clear advantages over bis-sulfone 2. This behavior might be due to the conformational and orbital control exerted by the tetrazole unit according to DFT calculations. Moreover, some alternative transformations to the Julia-Kocienski olefination on the obtained products are also described.

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Einige Valene von benzanellierten fünfgliedrigen Heteroarenen – Synthesen und NMR‐Spektren

Abstract: Die IH-NMR-Spektren von la und lb in schwach koordinierenden Lösungsmitteln (CD 2 CI 2 , CDCI 3 , [Da]

Cited by 3 publications

References 14 publications

4-(Phenylsulfanyl)tricyclo[3.1.0.02,6]hexan-3-one: Synthesis, Alkylation, and Base-Induced Dimerisation

4-(Phenylsulfanyl)tricyclo[3.1.0.02,6]hexan-3-one: Synthesis, Alkylation, and Base-Induced Dimerisation

ChemInform Abstract: Some Valenes of Benzoanellated Five‐Membered Heteroarenes ‐ Syntheses and NMR Spectra.

Expanding the Potential of Heteroaryl Vinyl Sulfones

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