Measuring energy spectra of nuclei after y-decay of excited states in flight the spin alignment of 12C2 + states has been measured. Inelastic scattering, 160(12 C, 12 C2 + ) 160 and the reaction 12C(~60, a2C2 +)16 0 leading to 12C 2 + (4.43 MeV) state have been studied. Characteristic line shapes of the 12C 2 + peak were observed using a Q3D magnetic spectrometer. The magnetic substate (m-states) population has been deduced from the spectra as function of reaction angle. A comparison of the measured m-state population with reaction models shows that the first reaction is consistent with inelastic scattering although discrepancies remain.Discrepancies are also obtained if the reaction 12C(160, 12C2+)160 is interpreted using a FRDWBA transfer calculation. At least 1/3 of the cross section can be attributed to ~-transfer. A calculation which couples transfer and inelastic scattering channels seems to be necessary.