Electric and magnetic properties of OCS measured by molecular-beam electric-resonance spectroscopy

Collisional Broadening of the J=7 ⇐ 6 Transition of t-Butyl Cyanide by CH3CN, OCS, CO2and Helium

“…For the mixture of pivalonitrile and CH3CN the main effect comes from the dipole-dipole and dipole-quadrupole interactions (μCΗ 3 CΝ = 3.913 D [11] and QCΗ3 CΝ = 1.8 DA [10,14]). The pivalonitrile and OCS mixture is similar (μOCS = 0.715 D [11] and QOCS = 5.58 DÅ [12]).…”

“…For the mixture of pivalonitrile and CH3CN the main effect comes from the dipole-dipole and dipole-quadrupole interactions (μCΗ 3 CΝ = 3.913 D [11] and QCΗ3 CΝ = 1.8 DA [10,14]). The pivalonitrile and OCS mixture is similar (μOCS = 0.715 D [11] and QOCS = 5.58 DÅ [12]). The dipole-quadupole interaction is most important in the collision process of carbon dioxide molecules (QCO 2 = 8.6 DA [13]) while in the collisions of helium atoms the dispersive interactions play the most important role.…”

The stark splitting of millimeter wave transitions of water

“…Whi le th e work has bee n in progress, an improved valu e of 0.71512 ± 0.00003 D has bee n publi s hed by De Leeuw and Dymanu s [6] . Th ese values are in excelle nt agreement, a nd th e accuracy of bot h exceeds th e precision of th e prese nt work.…”

The Rotational g Tensor as a Benchmark for Density-Functional Theory Calculations of Molecular Magnetic Properties

“…The four exceptions are OCS, ClCN, O 3 , and SO 2 , which all arise from the work of Dymanus and co-workers. [63][64][65][66] For OCS, the data of ref 63 is included, since three isotopes are studied whereas Flygare only reported two. The magnitude of the experimental g tensors and associated error bars is consistent for the two isotopes reported in both references.…”