In the framework of the electroweak chiral Lagrangian, the one-loop induced effects of the anomalous tbW coupling, which includes both left-and right-handed complex components, on the static electromagnetic properties of the W boson and the t quark are studied. The attention is focused mainly on the CP-violating electromagnetic properties. It is found that the tbW anomalous coupling can induce both CP-violating moments of the W boson, namely, its electric dipole (e µW ) and magnetic quadrupole ( e QW ) moments. As far as the t quark is concerned, a potentially large electric dipole moment (dt) can arise due to the anomalous tbW coupling. The most recent bounds on the left-and right-handed parameters from B meson physics lead to the following estimates e µW ∼ 4 × 10 −23 − 4 × 10 −22 e· cm and e QW ∼ 10 −38 − 10 −37 e· cm 2 , which are 7 and 14 orders of magnitude larger than the standard model (SM) predictions, whereas dt may be as large as 10 −22 e·cm, which is about 8 orders of magnitude larger than its SM counterpart.