Transmission electron microscopy has been used to investigate the formation and modification of the nanocrystalline silicon ( nc -Si) phase in thin a -Si:H films. The films were produced by three different methods: plasmochemical deposition of a-Si:H, cyclic plasmochemical deposition with intermediate annealing of layers 10-20 nm in thickness in hydrogen plasma, and plasmochemical deposition of a -Si:H with the annealing of 40-nm-thick films in hydrogen plasma. In the films produced by cyclic deposition with intermediate annealing in hydrogen plasma and subsequent thermal treatment at 750 ° C for 30 min, the size of nanocrystallites does not exceed the thickness of a layer deposited in a cycle. In contrast, in uniform films with similar thermal treatment, crystallites may be as large as 1 µ m or more. Models that account for the effects observed are suggested. These models are validated by calculating profiles of hydrogen diffusion in a -Si:H film after annealing in hydrogen plasma and thermal treatment in vacuum. © 2004 MAIK "Nauka/Interperiodica".
nmFig. 1. Cross-sectional TEM image of a -Si:H film produced by cyclic deposition.