1948
DOI: 10.1109/t-aiee.1948.5059649
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Electrical Insulation Deterioration Treated as a Chemical Rate Phenomenon

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Cited by 415 publications
(157 citation statements)
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“…This model was first introduced in [7] and it relates the thermal ageing to the rate of a temperature dependent chemical reaction, through the use of the Arrhenious equation. Thermo-mechanical ageing is mainly due to mechanical shear stress between the conductor surface and the insulation.…”
Section: The Multi-stress Ageing Modelmentioning
confidence: 99%
“…This model was first introduced in [7] and it relates the thermal ageing to the rate of a temperature dependent chemical reaction, through the use of the Arrhenious equation. Thermo-mechanical ageing is mainly due to mechanical shear stress between the conductor surface and the insulation.…”
Section: The Multi-stress Ageing Modelmentioning
confidence: 99%
“…Ageing in insulation of wound components is usually defined as the reduction in the function of the insulating materials [18]. The insulation lifetime is defined when the insulation properties of wound components deteriorate to values such that the wound components cannot operate satisfactory.…”
Section: Thermal Ageing Modelmentioning
confidence: 99%
“…Physical chemists looked at the rate of change of the concentration of certain constituents in chemical combinations in organic materials as a function of time and temperature [18]. This approach can be employed to organic electrical insulation deterioration if we know or assume that the physical properties of the insulation material is proportional to the concentration of an important constituent [18].where: P is the magnitude of the physical property in which we are interested in and C is the concentration of an important chemical constituent of the insulation materials which is being changed by the thermal stresses.The instantaneous rate of change of the number of molecules undergoing transformation with time is proportional to the number of the molecules. This relates to the chemical reactions of oxidising decomposition, polymerization, bridging and evaporation of plasticiser [18]: where: k is the reaction rate constant n is the order or rank of the reaction and t is the time.…”
mentioning
confidence: 99%
“…Consequently, for a particular insulation material there will be a temperature beyond which it would not be safely operated. UL and IEC treat this by establishing temperature classes and assigning each insulation material to a particular temperature class, but there are three problems with the way that this is executed: (1) The class rating methodology is based on a 1948 paper [17] and has not been reexamined for more than half a century. (2) The UL methodology [18] allows classification by experience of "field performance" without any laboratory testing.…”
Section: Temperature Class Of Insulation and Deterioration Due To Agingmentioning
confidence: 99%