The mass spectrometric study of the evaporation of As and P, respectively, during contacting of GaAs and GaP diodes was reported at the 7th International Vacuum Congress (u 1977). ~ow new results obtained on various contact-erystal systems ate presente& A laboratory SIMS system was built using a Riber QML 51 quadrupole mass speetrometer. The study of contacting processes was followed by SIMS in depth profiling of the contact-GaAs layer structures. Some SIMS studies of SiO 2 layers prepared by various methods ate described.