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ABSTRACTMethodology for efficient growth of semiconductor nanowires of several II-VI (ZnSe, ZnO, ZnS) and III-VI (GaAs, InSb) nanowires was developed and optimized. Based on optical and transport characterization measurements, defect states responsible for quenching of band-edge luminescence were identified and post-growth treatments were devised to eliminate those defects and to achieve strong excitonic emission. Carrier trapping dynamics was elucidated by ultrafast time-resolved optical pump-probe measurements. Optimized ZnSe nanowires were shown to exhibit an exceptionally high photoconductive response of 22A/W in a single nanowire transistor device. Manganese doped ZnO nanowires were fabricated and above room temperature ferromagnetism was achieved. Transport measurements showed these wires to be n-type with a degenerate carrier distribution. The experimental efforts were supplemented by modeling that included design of high Q-factor nanowire array photonic cavities using as well as a theory of excitons in nanowires.
1S. SUBJECT TERMS