1980
DOI: 10.1063/1.328117
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Electrical properties of polycrystalline GaAs films

Abstract: Electrical properties of Se-and Zn-doped polycrystalline GaAs deposited by metal organic chemical vapor deposition on substrates of polycrystalline alumina and glass were investigated. Hall-effect and resistivity measurements were made over a wide range of temperature (77-420 K). The electrical activation energies were found by measuring the variation of resistivity and carrier mobility of the polycrystalline GaAs films with sample temperature. The resistivity and mobility were found to be temperature activate… Show more

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Cited by 45 publications
(5 citation statements)
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“…Because the mobility was measured at the peak of the photoconductivity decay curve, prior to the charge recombination, diffusion, and photon reabsorption, the experimental mobility is independent of those processes (however, when analyzing the charge-carrier decay dynamics after t = 0, it is crucial to take into account the effect of such charge-carrier diffusion and photon reabsorption, as will be discussed later). While the charge-carrier mobility of the thin film is almost half that of the single-crystal MAPbI 3 sample, it does not show the three order-of-magnitude drop in mobility seen between single-crystal and polycrystalline GaAs, 47,48 indicating that grain boundaries may be more benign in MHPs. Moreover, because the THz measurements are sensitive to the surface conditions, the presence of surface defects on the single crystal can result in an underestimated mobility value.…”
mentioning
confidence: 82%
“…Because the mobility was measured at the peak of the photoconductivity decay curve, prior to the charge recombination, diffusion, and photon reabsorption, the experimental mobility is independent of those processes (however, when analyzing the charge-carrier decay dynamics after t = 0, it is crucial to take into account the effect of such charge-carrier diffusion and photon reabsorption, as will be discussed later). While the charge-carrier mobility of the thin film is almost half that of the single-crystal MAPbI 3 sample, it does not show the three order-of-magnitude drop in mobility seen between single-crystal and polycrystalline GaAs, 47,48 indicating that grain boundaries may be more benign in MHPs. Moreover, because the THz measurements are sensitive to the surface conditions, the presence of surface defects on the single crystal can result in an underestimated mobility value.…”
mentioning
confidence: 82%
“…Therefore, a lot of studies have been conducted on GBs in solar cell materials, such as polycrystalline Si and chalcopyrite semiconductors to improve efficiency. [13][14][15][16][17][18][19][20][21][22][23][24][25][26] One of the powerful tools for studying GBs properties is Kelvin probe force microscopy (KFM) method. Measurements with KFM yield the electrostatic properties of GBs and are used to determine the band diagrams across GBs.…”
mentioning
confidence: 99%
“…20 The energy distribution of defect states is experimentally hardly accessible. 25 In this work, we assume a constant distribution of defects within the band gap. 16 and 21.…”
Section: B Calculation Of the Barrier Height At Internal Boundaries mentioning
confidence: 99%