“…Because the mobility was measured at the peak of the photoconductivity decay curve, prior to the charge recombination, diffusion, and photon reabsorption, the experimental mobility is independent of those processes (however, when analyzing the charge-carrier decay dynamics after t = 0, it is crucial to take into account the effect of such charge-carrier diffusion and photon reabsorption, as will be discussed later). While the charge-carrier mobility of the thin film is almost half that of the single-crystal MAPbI 3 sample, it does not show the three order-of-magnitude drop in mobility seen between single-crystal and polycrystalline GaAs, 47,48 indicating that grain boundaries may be more benign in MHPs. Moreover, because the THz measurements are sensitive to the surface conditions, the presence of surface defects on the single crystal can result in an underestimated mobility value.…”