2,3‐Naphthalocyaninatoiron(II) (2,3‐NcFe) (1) is reacted with L = 1,4‐diisocyanobenzene (dib), tert‐butylisocyanide (t‐buNC), cyclohexylisocyanide (c‐hxNC), benzylisocyanide (bzNC), pyrazine (pyz), 4,4′‐bipyridine (bpy) and pyridine (py) to form the corresponding bis‐axially coordinated 2,3‐naphthalocyaninatoiron(II) compounds, 2,3‐NcFeL2 3, 4, 5, 6, 7, 8, 9. All 2,3‐NcFeL2‐complexes are characterized by IR‐, and if soluble enough by 1H‐NMR‐ and UV/VIS‐spectroscopy, TG/DTA‐measurements and elemental analyses. The dc‐room temperature conductivities of the 2,3‐NcFeL2‐complexes are measured and found to be several orders of magnitude higher than the corresponding phthalocyaninato‐iron‐complexes PcFeL2.