No abstract

No abstract

Good semiconductor properties are exhibited by stable bridged metal complexes containing s‐tetrazine as an N‐donor ligand. Square‐planar metal complexes, for example, phthalocyaninatoruthenium(II) and 2,3‐naphthalocyaninatoiron(II), may be bridged. The structure of this hexcoordinated bridged polymer is indicated in formula 1.

The bridged complexes (Ia) and (Ic) are prepared by reaction of the monomeric phthalocyaninato‐ or naphthalocyaninatometal compounds with a small excess of s‐tetrazine at 70 ° or 50 °C in CHCl3 for one or two days.

No abstract