This work presents the nonlinear dynamical analysis of a multilayer d31 piezoelectric macrofiber composite (MFC) laminated shell. The effects of transverse excitations and piezoelectric properties on the dynamic stability of the structure are studied. Firstly, the nonlinear dynamic models of the MFC laminated shell are established. Based on known selected geometrical and material properties of its constituents, the electric field of MFC is presented. The vibration mode-shape functions are obtained according to the boundary conditions, and then the Galerkin method is employed to transform partial differential equations into two nonlinear ordinary differential equations. Next, the effects of the transverse excitations on the nonlinear vibration of MFC laminated shells are analyzed in numerical simulation and moderating effects of piezoelectric coefficients on the stability of the system are also presented here. Bifurcation diagram, two-dimensional and three-dimensional phase portraits, waveforms phases, and Poincare diagrams are shown to find different kinds of periodic and chaotic motions of MFC shells. The results indicate that piezoelectric parameters have strong effects on the vibration control of the MFC laminated shell.