Electrocarboxylation of chloroacetonitrile by a Cobalt(I) complex of terpyridine

Solvent Effect on Electrochemical Properties of a Co(II)‐Based Metallo‐Supramolecular Polymer Film

“…In our previous study, polyCo exhibits an reversible redox couple in the reduction domain, which is assigned to the electron transfer at the metallic centre of Co(II)/Co(I) . The redox behaviour is dissimilar to our previous study in acetonitrile solution .…”

“…Electrochemical Properties In our previous study, [14] polyCo exhibits an reversible redox couple in the reduction domain, which is assigned to the electron transfer at the metallic centre of Co(II)/ Co(I). [19][20][21] The redox behaviour is dissimilar to our previous study in acetonitrile solution. [18] More discussion is made in the next section to investigate the electrochemical difference of polyCo film between switching in water and acetonitrile solution.…”

Terpyridine complexes of first row transition metals and electrochemical reduction of CO2 to CO

“…55 Similarly, we propose that ligand reduction triggers the loss of the second (neutral) terpyridine ligand, as supported by the Ni-tpy CVs at slow scan rates and as has been proposed for analogous cobalt-based systems. 56 The proposed mechanism for Co-tpy is depicted in Scheme 2,…”

Electrocarboxylation of Dichlorobenzenes on a Silver Electrode in DMF

“…However, Hg is discarded for environmental reasons. Meanwhile, studies have indicated that silver (Ag) exhibits extraordinary electrocatalytic activities toward the reduction of organic halides [13,[18][19][20][21][22][23]43,44]. Although many studies have investigated electroreduction and electrocarboxylation of organic chlorides, most of them focused on monochloride compounds [19,21,22,[40][41][42][43][44].…”