Electrochemical and In Situ Spectroscopic Evidences toward Empowering Ruthenium-Based Chalcogenides as Solid Acid Fuel Cell Cathodes

Abstract

A low-cost Ru-based chalcogenide catalyst has been used as a cathode catalyst in solid acid fuel cells (SAFC). With sequential addition of Se and Mo on Ru/C in a controlled manner, the resulting physical and electrochemical properties have been discussed in detail. The oxygen reduction reaction (ORR) in the presence of phosphoric acid has been performed to appraise the tolerance of the catalyst in the presence of phosphate anions. Considering the phosphate-rich environment during cell operation, this study is especially relevant for designing catalysts for s. In order to estimate the coverage of phosphate anions on active sites, a semiquantitative analysis of the corresponding Tafel plots has been done. Electrochemical, thermogravimetric, and in situ X-ray absorption spectroscopic experiments have been performed to get a deeper perception of the catalyst–electrolyte interface and account for the high stability of the chalcogenide catalyst at room temperature as well as at elevated temperature. Steady-state polarization curves in SAFC have been collected for over 120 h using the chalcogenide catalyst operating at 250 °C.

Interfacial water engineering boosts neutral water reduction

“…As observed in the Ru K-edge XANES (X-ray absorption near-edge structure) spectra (Supplementary Fig. 23), the comparison of RuNC and RuSe x with Ru foil and RuO 2 references imply that the Ru in RuSe x is only partially oxidized and mainly in metallic state, whereas the Ru single atoms in RuNC are positively charged, which agrees well with previous results 37,38 . Notably, the Ru K-edge position and the white line intensity of RuSe x -RuNC are between those of RuSe x and RuNC, implying the combined contributions from RuSe x and RuNC.…”

Nest-like NiCoP for Highly Efficient Overall Water Splitting

“…Accordingly, earth-abundant 3d transition metal (Co, Ni, Fe, Mn, V, etc.) alloys, − and their chalcogenides, − carbides, − nitrides, , and phosphides − have been widely explored to replace the noble metal based catalysts. Among them, transition metal phosphides (TMPs) with unique charged natures (positive and negative charges in metal and phosphorus, respectively), have attracted special attention due to the high catalytic activity derived from their hydrogenase-like catalytic mechanism .…”