2008
DOI: 10.1007/s11668-008-9180-3
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Electrochemical Formation of a Failure Preventing Film on Nickel Surface in Borate Solutions

Abstract: Cyclic voltammograms (CVs) of the Ni electrode are traced in Na 2 B 4 O 7 solutions as a function of electrolyte concentration, voltage scanning range, and rate in order to determine the nature of failure protective species formed in the slightly alkaline media. The species formed on the Ni electrode are found to depend on the sweep number due to changes in the activation state of the electrode surface. The voltammograms are characterized by a pronounced anodic peak due to the formation of NiO and a protective… Show more

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