Electrochemical in-situ synthesis of Cu/ICM-101 films for functional energetic chips

Electrochemical Synthesis of the Energetic Combustion Catalyst Co(BODN)·9H2O and Its Catalytic Effect on Ammonium Perchlorate Thermal Decomposition

“…In this work, Co­(BODN)·9H 2 O (BODN = [2,2′-bi­{1,3,4-oxadiazole}]-5,5′-dinitramide) was synthesized through electrochemical in situ synthesis, which provides a novel approach to synthesizing energetic combustion catalysts. Electrochemical synthesis was designed because it is not only simple, green, and efficient, but it can also effectively control the thickness and size of the generated crystals by adjusting the reaction time, voltage, and current . BODN was selected as the ligand because it exhibits excellent energy performance.…”

“…Electrochemical synthesis was designed because it is not only simple, green, and efficient, but it can also effectively control the thickness and size of the generated crystals by adjusting the reaction time, voltage, and current. 43 BODN was selected as the ligand because it exhibits excellent energy performance. Its theoretical density, heat of formation, detonation pressure, and detonation velocity can reach as high as 1.99 g•cm −3 , 166.8 kJ•mol −1 , 41.9 GPa, and 9481 m•s −1 , 44 respectively.…”