Electrochemical mineralization of perfluorooctane sulfonate by novel F and Sb co-doped Ti/SnO 2 electrode containing Sn-Sb interlayer

Yang, Bo; Wang, Jinbao; Jiang, Chaojin; Li, Juying; Yu, Gang; Deng, Shubo; Lu, Shaoyou; Zhang, Peixin; Zhu, Caizhen; Zhuo, Qiongfang

doi:10.1016/j.cej.2017.01.105

Cited by 85 publications

(27 citation statements)

References 40 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Components (e.g., F, Ni, Bi, Fe, Ru, Co, Ce, Pd, TiN) often work as co-dopants to improve the performance of Sb-SnO 2 electrode. 65,[69][70][71] Yang et al 65 showed high capacity toward the generation of active oxidants such as chlorine, ozone, and free radicals. 88 Kaur and co-authors 86…”

Section: Sno 2 -Based Catalystsmentioning

confidence: 99%

Recent advances in electrocatalysts for halogenated organic pollutant degradation

Chen

Liu

Wei

et al. 2019

Environ. Sci.: Nano

View full text Add to dashboard Cite

show abstract

Section: Sno 2 -Based Catalystsmentioning

confidence: 99%

Recent advances in electrocatalysts for halogenated organic pollutant degradation

Chen

Liu

Wei

et al. 2019

Environ. Sci.: Nano

View full text Add to dashboard Cite

show abstract

“…The Sb 3d core-level spectrum contains double peaks with binding energies of 530.8 and 540.1 eV, respectively, corresponding to Sb 3d 5/2 and Sb 3d 3/2 , as shown in Figure b. However, Sb 3d 3/2 can also be divided into characteristic peaks I and II, implying that Sb is present as mixed valence Sb 5+ and Sb 3+ in the SnO 2 lattice Figure c shows the binding energy spectrum of Fe 2p which can be fitted into four parts: Fe 3+ : (2p 3/2 : 710.2 eV; 2p 1/2 : 724.5 eV), Fe 2+ : (2p 3/2 :708.5 eV; 2p 1/2 :722.3 eV), Fe satellite peaks (715.2, 728.6 eV), and Sn 2p 3/2 :716.7 eV.…”

Section: Resultsmentioning

confidence: 98%

Oxygen Vacancy as a Medium-Induced Ferromagnetism in (Fe, Sb) Codoped SnO₂ Films

Xue

Liu

2018

J. Phys. Chem. C

View full text Add to dashboard Cite

(Sn0.97–x Sb0.03Fe x )O2 films (x = 0, 0.024, 0.046, and 0.073) were prepared by radio frequency magnetron sputtering. The structural environment, electrical transport, and magnetic behavior of the films were studied by X-ray diffractometer, X-ray photoelectron spectroscopy (XPS), X-ray absorption near-edge structure, physical property measurement system, electron paramagnetic resonance (EPR), and superconducting quantum interference methods. All of the films exhibited the tetragonal rutile structure of SnO2 by X-ray diffraction. XPS and extended X-ray absorption fine structure measurements revealed that Fe-doping ions substitute for Sn4+ sites of SnO2 lattice with a mixed-valence (Fe2+/Fe3+) and no trace of Fe cluster or second phases are in the doped system. The electrical transport measurement showed that the films have a typical semiconductor characteristic and that the carrier concentration n c decreases monotonically with Fe-doped concentration, and the carriers are strongly localized. Magnetic measurement showed that the saturation magnetization of the films increases regularly with Fe-doped concentration at room temperature. On the basis of EPR analysis, with an increase of Fe-doped concentration, the number of oxygen vacancies (Vo +) increases. The oxygen vacancies result in a long-range ferromagnetic ordering of the codoped SnO2 films. The origin of ferromagnetism of the codoped SnO2 films can be attributed to bound magnetic polaron mechanism.

show abstract

“…The diffraction peaks of SnO 2 were observed at 53.143°, 63.298°(JCPDS card 50-1429) and 26.495°, 33.727°(JCPDS card 46-1088). Doping of Sb ions in SnO 2 coating could not be clearly discerned through the XRD spectrum (Yang et al 2017), the reasons might be: 1. The Sb content was too low to be detected by XRD; 2.…”

Section: Physicochemical Characterizationmentioning

confidence: 99%

Facile synthesis of highly active Ti/Sb-SnO2 electrode by sol-gel spinning technique for landfill leachate treatment

Zhang

et al. 2021

Water Science and Technology

View full text Add to dashboard Cite

Highly active Ti/Sb–SnO2 electrodes were fabricated using sol-gel spin coating procedure, which exhibited a rough, uniform and multilayer coating structure. The effects of different Sb-SnO2 film layers on the physiochemical, electrochemical properties and pollutant degradability of electrodes and the mechanism were evaluated on a systematic basis. The electrodes with more active layers exhibited higher electro-catalytic performance. Upon exceeding 8 layers, the promotion effect of the coating was reduced. Considering various factors, this paper recommends preparing Ti/Sb–SnO2 electrodes coated with 8 layers to obtain higher electro-catalytic ability in landfill leachate treatment. The specific number of coating layers should be determined according to the electrode requirements. This work provided a theoretical basis and technical support for the preparation of Ti-SnO2 electrodes with high electro-catalytic activity and stability, while it still remains a great challenge to achieve an excellent balance between performance and stability before Ti/Sb-SnO2 electrodes can be implemented on a large scale in wastewater treatment.

show abstract

Electrochemical mineralization of perfluorooctane sulfonate by novel F and Sb co-doped Ti/SnO 2 electrode containing Sn-Sb interlayer

Cited by 85 publications

References 40 publications

Recent advances in electrocatalysts for halogenated organic pollutant degradation

Recent advances in electrocatalysts for halogenated organic pollutant degradation

Oxygen Vacancy as a Medium-Induced Ferromagnetism in (Fe, Sb) Codoped SnO₂ Films

Facile synthesis of highly active Ti/Sb-SnO2 electrode by sol-gel spinning technique for landfill leachate treatment

Contact Info

Product

Resources

About

Electrochemical mineralization of perfluorooctane sulfonate by novel F and Sb co-doped Ti/SnO 2 electrode containing Sn-Sb interlayer

Cited by 85 publications

References 40 publications

Recent advances in electrocatalysts for halogenated organic pollutant degradation

Recent advances in electrocatalysts for halogenated organic pollutant degradation

Oxygen Vacancy as a Medium-Induced Ferromagnetism in (Fe, Sb) Codoped SnO2 Films

Facile synthesis of highly active Ti/Sb-SnO2 electrode by sol-gel spinning technique for landfill leachate treatment

Contact Info

Product

Resources

About

Oxygen Vacancy as a Medium-Induced Ferromagnetism in (Fe, Sb) Codoped SnO₂ Films