Electrochemical property of multi-layer anode supported solid oxide fuel cell fabricated through sequential tape-casting and co-firing

Chen, Xiaoyang; Ni, Weijie; Du, Xiaojia; Sun, Zaihong; Zhu, Tenglong; Zhong, Qin; Han, Min−Koo

doi:10.1016/j.jmst.2018.10.015

Cited by 42 publications

(20 citation statements)

References 31 publications

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“…1-200 μm Simple, fast method, any shape of substrate is doable Choice of solvent media must be chosen carefully [185,202] Tape casting 10-1000 μm Cost-effective, simple, offers large-scale production Slower drying process, crack easily [197,199,200,212] Dry pressing 1-100 μm Simple, reproducible Not suitable for mass production, crack easily after sintering [98,202] Tape calendaring 5-200 μm Vary in thickness, good interfacial structure between the anode and the electrolyte Involving multiple layers for lamination [182,202,214] 3D-printing -Flexible, cost-effective, fast fabrication method Size limitation, high-cost investment for 3D printer, imperfection output image [83] 3D-printing Stereolithography (SLA)…”

Section: Advantages and Disadvantages Of Various Deposition Methodsmentioning

confidence: 99%

A review on the preparation of anode materials and anode films for solid oxide fuel cell applications

Hadi

Somalu

Osman

et al. 2021

Intl J of Energy Research

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The primary components of SOFCs are the anode, cathode, and the electrolyte. Anode is critical in achieving the effective electrochemical oxidation of fuel; thus, its performance can be improved using homogenous powder synthesized through an appropriate method. Various synthesis methods, including solidstate reaction and wet chemical methods have been used to synthesize anode materials. However, each technique has several advantages and disadvantages.Given that anode is a porous electrode, few criteria, such as high conductivity, tolerance towards carbon deposition, chemical stability, and thermal stability, must be fulfilled. Researchers also modified the existing synthesis method to improve the performance of the anode. In addition, various anode fabrication techniques including physical and colloidal deposition techniques are briefly discussed to understand their effect on the performance of the deposited layers.The aim of this review is to discuss the various anode synthesis and deposition techniques and their influence on the properties and performance of SOFCs.

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Section: Advantages and Disadvantages Of Various Deposition Methodsmentioning

confidence: 99%

A review on the preparation of anode materials and anode films for solid oxide fuel cell applications

Hadi

Somalu

Osman

et al. 2021

Intl J of Energy Research

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“…In state‐of‐the‐art solid oxide fuel cells (SOFCs), yttria‐stabilized cubic zirconia (YSZ) was used as electrolyte, because of its high ionic conductivity in the temperature range of 800–1,000 °C . However, the conductivity decreased rapidly with increasing temperature above 800 °C, making it unsuitable for practical applications for intermediate temperature solid oxide fuel cells (IT‐SOFCs) .…”

Section: Introductionmentioning

confidence: 99%

Enhancement of Electrochemical Properties, Impedance and Resistances of Micro‐tubular IT‐SOFCs with Novel Asymmetric Structure Based on BaZr_0.1Ce_0.7Y_0.1Yb_0.1O₃₋_δ Proton Conducting Electrolyte

et al. 2019

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Anode‐supported micro‐tubular SOFCs based on a proton and oxide ion mixed conductor electrolyte, BaZr0.1Ce0.7Y0.1Yb0.1O3−δ (BZCYYb), have been successfully fabricated via phase‐inversion process. Typical micro‐tubular cell with the configuration of Ni‐BZCYYb|BZCYYb|La0.6Sr0.4Co0.2Fe0.8O3–δ, consists of anode support, electrolyte and cathode with thicknesses of 200, 12, and 10 μm, respectively. The cells show excellent electrochemical performance with the peak power densities of 1.040, 0.902, 0.721, and 0.590 W cm−2 at 750, 700, 650, and 600 °C, respectively, with humidified (3 vol.% H2O) hydrogen as fuel and ambient air as oxidant. The AC impedance spectroscopy result shows low concentration polarization values of 0.016–0.021 Ω cm2 at 750–600 °C. Further, significant performance enhancement is observed during long‐term stability test at 600 and 750 °C under constant voltage of 0.5 and 0.7 V over 120 h, respectively, indicating excellent stability of BZCYYb under fuel cell operating condition. The high performance is attributed to high‐quality cell, validated by the dense, crack‐free BZCYYb electrolyte film supported by the anode with micro sponge‐like pores.

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“…This phenomenon might be caused by the concentration polarization within the porous layer. , Future research may further unleash the potential of bilayer NZMSP membranes by thinning the dense layer (to decrease the area resistance) while increasing the porosity and reducing the thickness of the support (to mitigate concentration polarization). Potential strategies to reduce the thickness of the support might include the following: (1) optimizing the pore-former and sintering process so that a free-standing membrane can be obtained with less starting material; , (2) using tape casting to prepare thinner membranes. , …”

mentioning

confidence: 99%

Recovery of Salinity Gradient Energy with an Inorganic Sodium Superionic Conductor

et al. 2022

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Solid inorganic electrolytes (SIEs) are promising materials for ion exchange membranes used in reverse electrodialysis (RED) processes to produce clean energy. However, SIEs have not yet been used in RED. Herein, Mg-substituted Na3Zr2Si2PO12 (NZMSP), an inorganic sodium superionic conductor, is used for the first time as a single-ion conducting ion exchange membrane in RED. The bilayer freestanding NZMSP membranes feature a sub-10-μm dense layer, delivering ultrahigh permselectivity (nearing 100%) and low resistance, along with improved power density compared to commercial cation exchange membranes. This work reports a new method to prepare high-performance SIE-based membranes. The enhanced power generation and permselectivity using this SIE membrane present a milestone in the field and will inspire further investigations.

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Electrochemical property of multi-layer anode supported solid oxide fuel cell fabricated through sequential tape-casting and co-firing

Cited by 42 publications

References 31 publications

A review on the preparation of anode materials and anode films for solid oxide fuel cell applications

A review on the preparation of anode materials and anode films for solid oxide fuel cell applications

Enhancement of Electrochemical Properties, Impedance and Resistances of Micro‐tubular IT‐SOFCs with Novel Asymmetric Structure Based on BaZr_0.1Ce_0.7Y_0.1Yb_0.1O₃₋_δ Proton Conducting Electrolyte

Recovery of Salinity Gradient Energy with an Inorganic Sodium Superionic Conductor

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Electrochemical property of multi-layer anode supported solid oxide fuel cell fabricated through sequential tape-casting and co-firing

Cited by 42 publications

References 31 publications

A review on the preparation of anode materials and anode films for solid oxide fuel cell applications

A review on the preparation of anode materials and anode films for solid oxide fuel cell applications

Enhancement of Electrochemical Properties, Impedance and Resistances of Micro‐tubular IT‐SOFCs with Novel Asymmetric Structure Based on BaZr0.1Ce0.7Y0.1Yb0.1O3−δ Proton Conducting Electrolyte

Recovery of Salinity Gradient Energy with an Inorganic Sodium Superionic Conductor

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Enhancement of Electrochemical Properties, Impedance and Resistances of Micro‐tubular IT‐SOFCs with Novel Asymmetric Structure Based on BaZr_0.1Ce_0.7Y_0.1Yb_0.1O₃₋_δ Proton Conducting Electrolyte