1994
DOI: 10.1007/bf00254151
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Electrochemical reduction of silver thiosulphate complexes Part II Mechanism and kinetics

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Cited by 12 publications
(12 citation statements)
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“…The electrolyte used for the electrodeposition of silver ions was prepared using sodium thiosulfate with sodium nitrate as stabilizing agent (30)(31)(32)(33). The solution consisted of 2 x 10 -3 M of AgNO 3 , 0.6 M of NaNO 3 and 3.65 x 10 -3 Mof Na 2 S 2 O 3 .…”
Section: Reactants and Materialsmentioning
confidence: 99%
“…The electrolyte used for the electrodeposition of silver ions was prepared using sodium thiosulfate with sodium nitrate as stabilizing agent (30)(31)(32)(33). The solution consisted of 2 x 10 -3 M of AgNO 3 , 0.6 M of NaNO 3 and 3.65 x 10 -3 Mof Na 2 S 2 O 3 .…”
Section: Reactants and Materialsmentioning
confidence: 99%
“…The major part of the investigations has been sacrificed to the most commonly used silver complexant in the classical processing, i.e., thiosulphate (S 2 O 2À 3 ), but alternatives such as thiocyanate, (SCN À ), or some thioethers -like 1,8-dihydroxy-3,6-dithiaoctane (DTO) -have also been studied. A state of the art description of the mechanism and kinetics is found in [3][4][5][6][7][8][9][10][11][12][13][14][15][16][17]. In the frame of the dry processes, completely different silver components like silver behenate (H 43 C 21 COOAg) are currently under investigation.…”
Section: Introductionmentioning
confidence: 99%
“…Extensive research work has already been carried out on the electrochemical reduction of silver complexes in imaging processes, using a variety of electrochemical and spectroscopic methods and data treatment techniques [3][4][5][6][7][8][9][10][11][12][13][14][15][16][17]. The major part of the investigations has been sacrificed to the most commonly used silver complexant in the classical processing, i.e., thiosulphate (S 2 O 2À 3 ), but alternatives such as thiocyanate, (SCN À ), or some thioethers -like 1,8-dihydroxy-3,6-dithiaoctane (DTO) -have also been studied.…”
Section: Introductionmentioning
confidence: 99%
“…By this choice, thermodynamic data on complex formation does not need to be included into the modeling. The predominant species are AgðS 2 O 3 Þ 3À 2 , AgðSCNÞ 2À 3 , and AgðDTOÞ þ 2 [12,13]. As will be explained below, the adsorption measurements with SERS and EIS in a sufficiently large potential domain require the use of solutions with varying silver and ligand concentrations.…”
Section: Solutionsmentioning
confidence: 99%