Electrochromic Materials and Devices 2013
DOI: 10.1002/9783527679850.ch3
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Electrochromic Materials and Devices Based on Viologens

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Cited by 46 publications
(43 citation statements)
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“…[10][11][12] From an electrochemical point of view, these dicationic compounds are subject to two consecutive Nernstian electron transfers 13 attributed to the successive formation of the cation radical V +• and neutral quinonic forms V 0 . The growing interest for viologen derivatives in supramolecular chemistry over the past decades thus mainly stems from the acceptor properties of the dicationic V 2+ 'ground' state and from the stability of the radical cation state 14 V +• which can both be implemented for the construction of supramolecular assemblies. [10][11][12]15,16 CB[n]s represent a specific class of barrel-shaped cavitands made of n glycoluril moieties connected by methylene bridges.…”
Section: Soluble Supramolecular Assembliesmentioning
confidence: 99%
“…[10][11][12] From an electrochemical point of view, these dicationic compounds are subject to two consecutive Nernstian electron transfers 13 attributed to the successive formation of the cation radical V +• and neutral quinonic forms V 0 . The growing interest for viologen derivatives in supramolecular chemistry over the past decades thus mainly stems from the acceptor properties of the dicationic V 2+ 'ground' state and from the stability of the radical cation state 14 V +• which can both be implemented for the construction of supramolecular assemblies. [10][11][12]15,16 CB[n]s represent a specific class of barrel-shaped cavitands made of n glycoluril moieties connected by methylene bridges.…”
Section: Soluble Supramolecular Assembliesmentioning
confidence: 99%
“…Other options include devices based on reversible electroplating [50], suspended particles [51], polymer-dispersed liquid crystals [52], metal hydrides [53], plasmonic effects in wide-bandgap electrically conducting nanoparticles [54][55][56], and solution-based systems [57]. It should also be noted that oxidebased materials are far from the only ones with EC properties and, in particular, there are a plethora of organic EC materials [58][59][60][61]. The latter ones are particularly well suited for display devices but most probably lack sufficient durability for uses in buildings.…”
Section: Introductionmentioning
confidence: 99%
“…Polypyrrole (PPY) is recognized as a conducting polymer that relies on its electrochemical responsive properties rather than on its chemical structure. PPY offers a potentially useful resource because it possesses optical, magnetic, and electronic properties comparable to those of metals or semiconductors, while also retaining its polymeric structure and properties, such as ease of processing, low toxicity, flexibility, and adjustable electrical conductivity [34,35,36,37,38,39,40]. However, the general applications of PPY have been mostly limited to date owing to its poor mechanical properties.…”
Section: Introductionmentioning
confidence: 99%