Electrodeposition of metals from non-aqueous solutions

Simka, Wojciech; Puszczyk, Dagmara; Nawrat, G.

doi:10.1016/j.electacta.2009.04.028

Cited by 276 publications

(164 citation statements)

References 169 publications

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“…In case of the other metal substrates cathodic peaks are not so distinct and there is difficult to fit anodic peaks to them what could indicate that same reduction reactions of zirconium ions are not reversible. Those differences depend on different conditions of adsorption upon different metals and on the different behaviours of the metals in the electrolyte [25]. Zirconium has been reported by several investigators to exist in many oxidation states in molten alkali halides.…”

Section: Resultsmentioning

confidence: 99%

Electrodeposition of Zirconium from DMSO Solution

Simka¹,

Majewski²,

Nawrat³

et al. 2014

Archives of Metallurgy and Materials

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ELEKTROOSADZANIE CYRKONU Z ROZTWORU DMSOInvestigations of voltammetry zirconium deposition from DMSO solution on different substrates were taken. It was found that this is multi-electron process proceeding in a few stages. Moreover, zirconium layers were obtained on titanium, copper stainless steel and nickel. Obtained deposit was in form of white powder, which immediately was oxidized to ZrO 2 in the presence of air.Keywords: zirconium; DMSO; electrodeposition; voltammetry W pracy przedstawiono badania woltamperometryczne procesu elektroosadzania cyrkonu z roztworu DMSO na różnych podłożach. Stwierdzono, że jest to procees wieloelektronowy zachodzący w kilku etapach. Ponadto otrzymano warstwy cyrkonu na tytanie, miedzi, stali kwasoodpornej i niklu. Wytworzony osad katodowy miał formę białego proszku, na skutek natychmiastowego utlenienia cyrkonu w kontakcie z powietrzem.

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Section: Resultsmentioning

confidence: 99%

Electrodeposition of Zirconium from DMSO Solution

Simka¹,

Majewski²,

Nawrat³

et al. 2014

Archives of Metallurgy and Materials

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“…Unlike aqueous electrolytes (where the metal ions solubility is limited by oxides/hydroxides precipitation), high solubility, and ligand concentrations can be achieved in water-free ionic liquids. Moreover, the high ligand concentrations ensure greater control on the metal speciation in the electrolyte [76,77]. Therefore, reline forms strong metal complexes with the ions, and hence, the necessity of using complexing agents is eliminated.…”

Section: Cise/cigse Electrodeposition In Non-aqueous Electrolytesmentioning

confidence: 99%

A short review on the advancements in electroplating of CuInGaSe2 thin films

Chandran

Panda

Mallik

2018

Mater Renew Sustain Energy

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Thin-film solar cell devices based on copper indium gallium diselenide (CIGSe) chalcogenide materials fabricated by vacuum-based deposition techniques have already achieved lab scale efficiency beyond 21%. For industrial-scale applications, non-vacuum deposition technique such as electrodeposition and screen printing is considered to be suitable approaches for reducing the device fabrication cost. Moreover, electrodeposition has the potential to prepare large area thin films as it requires cheap raw material sources and equipment capital. Hence, it is imperative to understand the current status and advancements in the electroplating techniques of the CIGSe thin films. This article reviews on the experimental advances in electroplating of ternary CuInSe 2 and quaternary CIGSe. Various approaches in electrodeposition, influential experimental parameters, and the deposition mechanisms which are related to the final cell efficiency are discussed in detail.

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“…A stable Au/Mg alloy has a work function lower than gold and it is remarkably resistant to the effects of water and air, which makes it well suited for application in contact anion [24,[26][27][28]. In addition, new ionic liquids proved to be suitable media for electrodeposition of metals and alloys at relatively low temperatures (from 273 to 373 K) [29][30][31].…”

Section: Introductionmentioning

confidence: 99%

Magnesium–Gold Alloy Formation by Underpotential Deposition of Magnesium onto Gold from Nitrate Melts

Cvetković

Jovićević

Stevanović

et al. 2017

Metals

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Magnesium underpotential deposition on gold electrodes from magnesium nitrate-ammonium nitrate melts has been investigated. Linear sweep voltammetry and potential step were used as electrochemical techniques. Scanning electron microscopy (SEM), energy dispersive spectrometry (EDS) and X-ray diffraction (XRD) were used for characterization of obtained electrode surfaces. It was observed that reduction processes of nitrate, nitrite and traces of water (when present), in the Mg underpotential range studied, proceeded simultaneously with magnesium underpotential deposition. There was no clear evidence of Mg/Au alloy formation induced by Mg UPD from the melt made from eutectic mixture [Mg(NO 3 ) 2 ·6H 2 O + NH 4 NO 3 ·XH 2 O]. However, EDS and XRD analysis showed magnesium present in the gold substrate and four different Mg/Au alloys being formed as a result of magnesium underpotential deposition and interdiffusion between Mg deposit and Au substrate from the melt made of a nonaqueous [Mg(NO 3 ) 2 + NH 4 NO 3 ] eutectic mixture at 460 K.

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Electrodeposition of metals from non-aqueous solutions

Cited by 276 publications

References 169 publications

Electrodeposition of Zirconium from DMSO Solution

Electrodeposition of Zirconium from DMSO Solution

A short review on the advancements in electroplating of CuInGaSe2 thin films

Magnesium–Gold Alloy Formation by Underpotential Deposition of Magnesium onto Gold from Nitrate Melts

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