“…Historically, the main thrust in the investigation into electrodeposition has been two-fold: Firstly improving corrosion resistance and, secondly, improving the wear resistance and mechanical properties of materials. In more recent times, these two demands continue to be of prominence; notwithstanding, a heightened research effort has gone into the study and development of processes for other areas of applications, such as magnetic properties [7][8][9][10][11][12][13][14][15][16][17][18][19] and catalysis, hydrogen permeability and separation [20][21][22][23][24][25][26][27][28][29], membrane technology, electronic devices, metallization of non-and semiconductors, and fuel cells . Furthermore, electrodeposition is one of the most convenient methods to obtain metal/alloys of high melting points, such as chromium (Cr, 1907 • C), nickel (Ni, 1455 • C), and molybdenum (Mo, 2623 • C) [54,55], even at ambient temperatures, of which the first two are of interest in this review.…”